VOCs species controlling O3 formation in ambient air and their sources in Kaifeng, China

Abstract

The concentration of ozone has been in a rising crescendo in the last decade while the fine particles (PM2.5) is gradually decreasing but still at a high level in central China. Volatile organic compounds (VOCs) are the vital precursors of ozone and PM2.5. A total of 101 VOC species were measured in four seasons at five sites from 2019 to 2021 in Kaifeng. VOC sources and geographic origin of sources were identified by the positive matrix factorization (PMF) model and the HYbrid Single-Particle Lagrangian Integrated Trajectory transport model. The source-specific OH loss rates (LOH) and ozone formation potential (OFP) were calculated to estimate the effects of each VOC source. The average mixing ratios of total VOCs (TVOC) were 43.15 parts per billion (ppb), of which the alkanes, alkenes, aromatics, halocarbons, and oxygenated VOCs respectively accounted for 49%, 12%, 11%, 14%, and 14%. Although the mixing ratios of alkenes were comparatively low, they played a dominant role in the LOH and OFP, especially ethene (0.55 s− 1, 7%; 27.11 µg/m3, 10%) and 1,3-butadiene (0.74 s− 1, 10%; 12.52 µg/m3, 5%). The vehicle-related source which emitted considerable alkenes ranked as the foremost contributing factor (21%). Biomass burning was probably influenced by other cities in the western and southern Henan and other provinces, Shandong and Hebei.

Biofiltration of toluene in the presence of ethyl acetate or n-hexane: Performance and microbial community

“…Additionally, ozone (O 3 ) pollution is becoming increasingly prevalent [ 2 ]. Volatile organic compounds (VOCs) are widely recognized as major precursors of O 3 and PM 2.5 , which have a serious impact on environmental quality and human health [ 3 ]. Toluene (T), ethyl acetate (EA), and n -hexane (H) are among the most frequently used as industrial solvents, and are major pollutants found in the exhaust air of printing facilities [ 4 , 5 ].…”