Visible Light Responsive Dinuclear Zinc Complex Consisting of Proximally Arranged Two d10‐Zinc Centers**
Yoshimasa Wada,
Takahiro Maruchi,
Reon Ishii
et al.
Abstract:So far, Zn(II)‐based d10 complexes have been known to be colorless unless they are accompanied by chromophoric groups, and therefore both fundamental and advanced photophysical performance of Zn centers of complexes, especially in visible‐light regions has been unexplored. Here, we first demonstrate a dinuclear Zn(II) complex that shows visible light absorption using an orbital distributed over closely contacted two Zn centers experimentally determined by X‐ray crystallography. A contrastive study demonstrated… Show more
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