Visible-light-responsive Ag/TiO2/PVA nanocomposite for photocatalytic degradation of Cr, Ni, Zn, and Cu heavy metal ions

Dehghani, Mohammadtaha; Delnavaz, Mohammad

doi:10.21203/rs.3.rs-1858836/v1

Cited by 2 publications

References 21 publications

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Preparation, Characterization, and Application of Novel Ternary PPS/PVA/Fe3O4 Nanocomposite for Enhanced Visible Light Photocatalytic Degradation of Methylene Blue

Atashkadi,

Mohadesi,

Karimi

et al. 2023

J Clust Sci

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This study used a simple co-precipitation method to fabricate a novel polymer-based photocatalyst that displayed effective photocatalytic activity towards the degradation of methylene blue (MB) solution under visible light irradiation. Due to its excellent properties, intrinsic polarization, and asymmetric structure, polyphenylene sul de (PPS) was utilized in the magnetic ternary PPS/PVA/Fe 3 O 4 nanocomposite. The analytical techniques con rmed the desirable combination of the photo-initiated Fe 3 O 4 nanoparticles as the strong oxidizers with the high adsorption capacity of PPS and the binding and conductive effects of polyvinyl alcohol (PVA). Binary nanocomposites of PPS/Fe 3 O 4 and PVA/Fe 3 O 4 were also prepared to compare their photocatalytic activities with that of the PPS/PVA/Fe 3 O 4 sample.The optimum degradation occurred in PPS/PVA/Fe 3 O 4 , reaching 83% after 120 minutes. Its superior activity was attributed to the synergistic interactions, such as broader absorption of visible light, suppression of electron-hole pair recombination, and increment in the surface area of the mesoporous catalyst. Based on the effects of scavengers, it was concluded that hydroxyl radicals had a vital role in the photodegradation of methylene blue. Kinetically, the photocatalytic activity of PPS/PVA/Fe 3 O 4 followed the pseudo-rst-order kinetic model, which was about 3.9 and 3.1 times greater than those of PPS and PPS/Fe 3 O 4 , respectively. More speci cally, the superparamagnetic behavior of PPS/PVA/Fe 3 O 4 helped to be recovered with an external magnetic eld and showed good reusability and stability after four successive runs. The current work suggests that PPS-based photocatalysts can provide promising opportunities for the photocatalytic degradation of organic pollutants and opens up a new perspective on water treatment.

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Preparation, Characterization, and Application of Novel Ternary PPS/PVA/Fe3O4 Nanocomposite for Enhanced Visible Light Photocatalytic Degradation of Methylene Blue

Atashkadi,

Mohadesi,

Karimi

et al. 2023

J Clust Sci

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show abstract

Preparation, Characterization, and Application of Novel Ternary PPS/PVA/Fe 3 O 4 Nanocomposite for Enhanced Visible Light Photocatalytic Degradation of Methylene Blue

Atashkadi

Mohadesi

Karimi

et al. 2023

Preprint

View full text Add to dashboard Cite

This study used a simple co-precipitation method to fabricate a novel polymer-based photocatalyst that displayed effective photocatalytic activity towards the degradation of methylene blue (MB) solution under visible light irradiation. Due to its excellent properties, intrinsic polarization, and asymmetric structure, polyphenylene sulfide (PPS) was utilized in the magnetic ternary PPS/PVA/Fe3O4 nanocomposite. The analytical techniques confirmed the desirable combination of the photo-initiated Fe3O4 nanoparticles as the strong oxidizers with the high adsorption capacity of PPS and the binding and conductive effects of polyvinyl alcohol (PVA). Binary nanocomposites of PPS/Fe3O4 and PVA/Fe3O4 were also prepared to compare their photocatalytic activities with that of the PPS/PVA/Fe3O4 sample. The optimum degradation occurred in PPS/PVA/Fe3O4, reaching 83% after 120 minutes. Its superior activity was attributed to the synergistic interactions, such as broader absorption of visible light, suppression of electron-hole pair recombination, and increment in the surface area of the mesoporous catalyst. Based on the effects of scavengers, it was concluded that hydroxyl radicals had a vital role in the photodegradation of methylene blue. Kinetically, the photocatalytic activity of PPS/PVA/Fe3O4 followed the pseudo-first-order kinetic model, which was about 3.9 and 3.1 times greater than those of PPS and PPS/Fe3O4, respectively. More specifically, the superparamagnetic behavior of PPS/PVA/Fe3O4 helped to be recovered with an external magnetic field and showed good reusability and stability after four successive runs. The current work suggests that PPS-based photocatalysts can provide promising opportunities for the photocatalytic degradation of organic pollutants and opens up a new perspective on water treatment.

show abstract

Visible-light-responsive Ag/TiO2/PVA nanocomposite for photocatalytic degradation of Cr, Ni, Zn, and Cu heavy metal ions

Cited by 2 publications

References 21 publications

Preparation, Characterization, and Application of Novel Ternary PPS/PVA/Fe3O4 Nanocomposite for Enhanced Visible Light Photocatalytic Degradation of Methylene Blue

Preparation, Characterization, and Application of Novel Ternary PPS/PVA/Fe3O4 Nanocomposite for Enhanced Visible Light Photocatalytic Degradation of Methylene Blue

Preparation, Characterization, and Application of Novel Ternary PPS/PVA/Fe 3 O 4 Nanocomposite for Enhanced Visible Light Photocatalytic Degradation of Methylene Blue

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