Visible light induced palladium-catalyzed reactions involving halogenated hydrocarbon (RX)

Dong, Dao‐Qing; Tian, Bao-ling; Yang, Hao; Wei, Ze-Hui; Yang, Shuhua; Zhou, Meng-Yu; Ding, Cai-Zhen; Wang, Yanli; Gao, Jia-Hui; Wang, Shujie; Yang, Wenchao; Liu, Baoting; Wang, Zu‐Li

doi:10.1016/j.mcat.2023.113073

Cited by 5 publications

(2 citation statements)

References 84 publications

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“…Feasible radical transformations including addition, cyclization, coupling, atom or group transfer, rearrangement, and fragmentation reactions have made radical reactions a powerful tool for making carbon-carbon and carbon-heteroatom bonds [ 1 , 2 ]. The recent developments in radical cyclative functionalization [ 3 , 4 ], radical-enabled bicyclization [ 5 ], photoredox reactions [ 6 , 7 , 8 ], mechanoredox reactions [ 9 ], electrochemical reactions [ 10 ], and transition metal-assisted radical reactions [ 11 , 12 , 13 , 14 ] have empowered the utility of synthetic radicals. Radical reactions being performed in a cascade sequence for the assembling of complex molecular scaffolds with multiple functional groups in regio- and diastereoselective manners is a unique feature.…”

Section: Introductionmentioning

confidence: 99%

Radical Cyclization-Initiated Difunctionalization Reactions of Alkenes and Alkynes

Zhi,

Ma,

Zhang

2024

Molecules

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Radical reactions are powerful in the synthesis of diverse molecular scaffolds bearing functional groups. In previous review articles, we have presented 1,2-difunctionalizations, remote 1,3-, 1,4-, 1,5-, 1,6- and 1,7-difunctionalizations, and addition followed by cyclization reactions. Presented in this paper is radical cyclization followed by the second functionalization reaction. The second functionalization could be realized by atom transfer reactions, radical or transition metal-assisted coupling reactions, and reactions with neutral molecules, cationic and anionic species.

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Section: Introductionmentioning

confidence: 99%

Radical Cyclization-Initiated Difunctionalization Reactions of Alkenes and Alkynes

Zhi,

Ma,

Zhang

2024

Molecules

View full text Add to dashboard Cite

show abstract

“…Feasible radical transformations including addition, cyclization, coupling, atom or group transfer, rearrangement, and fragmentation reactions have made radical reactions a powerful tool for making carbon-carbon and carbon-heteroatom bonds [1,2]. The recent development on radical cyclative functionalization [3,4], radical-enabled bicyclization [5], photoredox reactions [6][7][8], mechanoredox reactions [9], electrochemical reactions [10], and transition metal-assisted radical reactions [11][12][13][14] have empowered the utility of synthetic radicals. It is a unique feature that radical reactions could be performed in a cascade sequence for the assembling of complex molecular scaffolds with multiple functional groups in regio-and diastereoselective manners.…”

Section: Introductionmentioning

confidence: 99%

Radical Cyclization-initiated Difunctionalization Reactions of Alkenes and Alkynes

Zhi,

Ma,

Zhang

2024

Preprint

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Radical reactions are powerful in the synthesis of diverse molecular scaffolds bearing functional groups. In pervious review articles, we have presented 1,2-difunctionalizations, remote 1,3-, 1,4-, 1,5-, 1,6- and 1,7-difunctionalizations, and addition followed by cyclization reactions. Presents in this paper are radical cyclization followed by the second functionalization reactions. The second functionalization could be realized by atom transfer reactions, radical or transition metal-assisted coupling reactions, and reactions with neutral molecules, cationic and anionic species.

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Progress in the decarboxylative deuteration reaction of alkyl carboxylic acids

Dong,

Yang,

Wang

et al. 2023

Applied Organom Chemis

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The application of deuterated compounds is increasingly expanding across various fields, making the development of novel deuterium labeling techniques for obtaining deuterated compounds a burgeoning research focus. Carboxylic acids and their derivatives are widely utilized as cost‐effective and readily available materials for obtaining deuterated compounds due to their stable properties. This article presents a comprehensive and concise summary of the research progress in decarboxylative deuteration reactions over the past 20 years.

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Visible light induced palladium-catalyzed reactions involving halogenated hydrocarbon (RX)

Cited by 5 publications

References 84 publications

Radical Cyclization-Initiated Difunctionalization Reactions of Alkenes and Alkynes

Radical Cyclization-Initiated Difunctionalization Reactions of Alkenes and Alkynes

Radical Cyclization-initiated Difunctionalization Reactions of Alkenes and Alkynes

Progress in the decarboxylative deuteration reaction of alkyl carboxylic acids

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