1957
DOI: 10.1002/pol.1957.1202611418
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Viscosity‐concentration relation of aminoacetalized polyvinyl alcohol sulfate in aqueous solution

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Cited by 3 publications
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“…Matsumoto and Eguchi 399 reported diluted viscosity data for aminoacetalyzed polyvinyl alcohol with different fractions of charged groups in salt-free water. As 0.1 M K 2 SO 4 is a near theta solvent for the uncharged polymer, 416 we expect water to be a marginally good solvent for the backbone and ξ T ≫ ξ el .…”
Section: Review Of Experimental Datamentioning
confidence: 99%
See 1 more Smart Citation
“…Matsumoto and Eguchi 399 reported diluted viscosity data for aminoacetalyzed polyvinyl alcohol with different fractions of charged groups in salt-free water. As 0.1 M K 2 SO 4 is a near theta solvent for the uncharged polymer, 416 we expect water to be a marginally good solvent for the backbone and ξ T ≫ ξ el .…”
Section: Review Of Experimental Datamentioning
confidence: 99%
“…S8, ESI †) do not agree with the scaling predictions. Further experimental work is needed in two regards: first, systematic work on the conformational and hydrodynamic properties as a function of charge fraction in salt-free solution is at present limited to two studies, 97,399 extension to other systems is vital if we are to understand the discrepancies between theory and experiment. Second, the scaling predicts x el o l K for polyelectrolytes with more than one dissociated charge per Kuhn segment, but experimental evidence (see Fig.…”
Section: Conclusion and Outstanding Questionsmentioning
confidence: 99%