“…Meyer et al [44] wrote that the excess Gibbs free energy of activation of viscous flow, like viscosity deviations, can be used to detect molecular interactions. As suggested by other authors [45][46][47][48], positive deviations of G ÃE 12 should be detected in binary mixtures, where strong specific interactions between unlike molecules take place over all other interactions of any kind, classifiable as dispersion forces, which generally are responsible for the negative deviation in the property.…”
“…Meyer et al [44] wrote that the excess Gibbs free energy of activation of viscous flow, like viscosity deviations, can be used to detect molecular interactions. As suggested by other authors [45][46][47][48], positive deviations of G ÃE 12 should be detected in binary mixtures, where strong specific interactions between unlike molecules take place over all other interactions of any kind, classifiable as dispersion forces, which generally are responsible for the negative deviation in the property.…”
“…For investigated mixtures, as the molecules size of the 1-alkanols increases the minima is getting sharper. This suggests that vary molecular interactions between the mixing molecules depend upon their sizes and shape [29,30]. The same dependencies are also observed at 298.15, 308.15, and 381.15 K, but these curves are not displayed so as to avoid any redundancy.…”
“…Canosa et al [12] introduced new parameter to correlate experimental data of ternary systems from binary ones. The viscosity of n-component mixture according to correlating equations [11,12] are as follows:…”
Section: Dynamic Viscositiesmentioning
confidence: 99%
“…The best correlation method for the ternary system was found using the Nagata equation. The viscosity data for the binary and ternary mixtures were fitted to Nissan and Grunberg [10][11][12], Hind et al [11][12][13][14], Katti and Chaudhri [11,12,15], McAllister [11,12,16], Heric [11,12,17], Frenkel [11,12,18], and Iulan et al [11,12,19] and their parameters have been calculated. Theoretical models dealing with liquid state including Jacobson free length theory (FLT) [20][21][22][23], Schaaff collision factor theory (CFT) [21,23,24], Nomoto relation (NR) [21,25], Junjie relation (JR) [21,26] and Van Deal ideal mixing relation (IMR) [21,27] have been proposed for the prediction of the speeds of sound and isentropic compressibilities of the binary and ternary mixtures.…”
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