Vibrational spectroscopic studies on the hofmann-Td-type clathrates: M(NH3)2M?(CN)4�2C6H6 (M=Mn or Cd and M?=Cd or Hg0

Kasap, E.; Kantarcı, Ziya

doi:10.1007/bf00707610

Cited by 18 publications

(1 citation statement)

References 27 publications

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“…Such frequency shifts have been observed for Hofmanntype host frameworks [21, [36][37][38][39][40][41][42][44][45][46][47] and are attributed to the mechanical coupling of the internal modes of Ni(CN) 4 with the M-NC vibrations. It follows that the Ntermini of the Ni(CN) 4 group are bound to a Cd atom in the host compound investigated.…”

Section: Vibrationsmentioning

confidence: 90%

Synthesis, IR spectrum, thermal property and crystal structure of cyano-bridged heteronuclear polymeric complex, [Cd(teta)Ni(μ-CN)2(CN)2] · 2H2O

et al. 2008

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The cyano-bridged heteronuclear polymeric complex, [Cd(teta)Ni(l-CN) 2 (CN) 2 ] Á 2H 2 O (1), (teta = triethylenetetraamine) was synthesized and characterized by FT-IR spectroscopy, thermal analysis and single crystal X-ray diffraction techniques. It crystallizes in the orthorhombic system, space group Pccn. The asymmetric unit also contains two uncoordinated water molecules. The coordination geometry around the Cd(II) centre is a highly distorted octahedral. In the crystal structure, intramolecular N-HÁÁÁO and intermolecular N-HÁÁÁO, O-HÁÁÁO and O-HÁÁÁN hydrogen bonds, beside the cyano-bridged chains made up of tetracyanonickelate ions coordinated to Cd(II) ions, where the Ni(II) ion is coordinated by four cyanoligands in a square-planar arrangement, link the molecules into polymeric networks parallel to (001) plane, where the hydrogen bonded water molecules occupy the cavities between the layers. The FT-IR spectrum was reported in the 4,000-400 cm -1 region. Vibration assignments were given for all the observed bands and the spectral feature also supported the structure of the polymeric complex. The decomposition reaction takes place in the temperature range 20-1,000°C in the static air atmosphere.

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Section: Vibrationsmentioning

confidence: 90%

Synthesis, IR spectrum, thermal property and crystal structure of cyano-bridged heteronuclear polymeric complex, [Cd(teta)Ni(μ-CN)2(CN)2] · 2H2O

et al. 2008

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Synthesis, IR Spectrum, Thermal Analysis, and Crystal Structure of the Cyano‐bridged Heteronuclear Polymeric Complex: [Zn(teta)Ni(μ‐CN)₂(CN)₂]_n

Kürkçüoğlu¹,

Yeşılel²,

Kavlak³

et al. 2008

Zeitschrift anorg allge chemie

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Vibrational spectroscopic studies on the en-Td-type benzene clathrates: M(ethylenediamine)M?(CN)4�2C6H6 (M=Mn or Cd, M?=Cd or Hg)

Kasap

Kantarcı

1995

J Incl Phenom Macrocycl Chem

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Vibrational spectroscopic studies on the hofmann-Td-type clathrates: M(NH3)2M?(CN)4�2C6H6 (M=Mn or Cd and M?=Cd or Hg0

Cited by 18 publications

References 27 publications

Synthesis, IR spectrum, thermal property and crystal structure of cyano-bridged heteronuclear polymeric complex, [Cd(teta)Ni(μ-CN)2(CN)2] · 2H2O

Synthesis, IR spectrum, thermal property and crystal structure of cyano-bridged heteronuclear polymeric complex, [Cd(teta)Ni(μ-CN)2(CN)2] · 2H2O

Synthesis, IR Spectrum, Thermal Analysis, and Crystal Structure of the Cyano‐bridged Heteronuclear Polymeric Complex: [Zn(teta)Ni(μ‐CN)₂(CN)₂]_n

Vibrational spectroscopic studies on the en-Td-type benzene clathrates: M(ethylenediamine)M?(CN)4�2C6H6 (M=Mn or Cd, M?=Cd or Hg)

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Vibrational spectroscopic studies on the hofmann-Td-type clathrates: M(NH3)2M?(CN)4�2C6H6 (M=Mn or Cd and M?=Cd or Hg0

Cited by 18 publications

References 27 publications

Synthesis, IR spectrum, thermal property and crystal structure of cyano-bridged heteronuclear polymeric complex, [Cd(teta)Ni(μ-CN)2(CN)2] · 2H2O

Synthesis, IR spectrum, thermal property and crystal structure of cyano-bridged heteronuclear polymeric complex, [Cd(teta)Ni(μ-CN)2(CN)2] · 2H2O

Synthesis, IR Spectrum, Thermal Analysis, and Crystal Structure of the Cyano‐bridged Heteronuclear Polymeric Complex: [Zn(teta)Ni(μ‐CN)2(CN)2]n

Vibrational spectroscopic studies on the en-Td-type benzene clathrates: M(ethylenediamine)M?(CN)4�2C6H6 (M=Mn or Cd, M?=Cd or Hg)

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Synthesis, IR Spectrum, Thermal Analysis, and Crystal Structure of the Cyano‐bridged Heteronuclear Polymeric Complex: [Zn(teta)Ni(μ‐CN)₂(CN)₂]_n