Vibrational Spectra of OsF6 and PtF6

Abstract

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TOPOLOGICAL ASPECTS OF THE CONFORMATIONAL STABILITY PROBLEM. PART I. DEGENERATE ELECTRONIC STATES1

“…14a,b,c,d] in place of the tetragonally oricntcd basis [ Fig. 3.2-4,5, and 6 , w e introduce trigonally oriented T~~ nuclear displacemcnts [Ipig.…”

“…Sa, b,c,d and lGa1 which replaees x by - y, y byz, z by -x, atom 0 by 3, 1 by 4, 2 by 1, 3 by 5, 4 by 0, and 5 by 2 (Pig. Sa, b,c,d and lGa1 which replaees x by - y, y byz, z by -x, atom 0 by 3, 1 by 4, 2 by 1, 3 by 5, 4 by 0, and 5 by 2 (Pig.…”

“…30a,b,c and eq. 29,32a,b,35a,b,and 8Ga,h] against that of the tetragonal geometry [Fig. Once in S,,b,c-space the nuclei roll off the rhombic saddle [I'ig.…”

“…3.2-12). 18a,b,c,d,e] is decided primarily by the relative order of magnitude of the constants CZ, ea, CZZ, and CSS.'~. 23, 24, 25, 27a, 28,31,33, 341 to the trigonal (relative) minima [Pig.…”

“…caption trigonal (relative) minimum [Fig. 23,24,26,29,32a,b,35a,b,36a,b] in Sb,b.ospace via a trek along the SzS.h-space intersection of Et with Eo and El, with a companion movement from the origin in S&.6+,-space [ Fig. 30a 24,26,28,31,33,341 or to a trigonal cusp or a trigonal (relative) minimum [Fig.…”