2003
DOI: 10.1103/physreva.68.032704
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Vibrational relaxation and dissociative recombination ofH2+induced by slow electrons

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Cited by 36 publications
(33 citation statements)
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“…In the case of weak coupling, a perturbative solution of equation (2.3) can be obtained. This solution has been recently proven to be exact to second order, in the case of energy-independent electronic coupling (Ngassam et al 2003b). In the external zone, the 'B-region ' (Jungen and Atabek 1977) represented by large electron-core distances, the Born-Oppenheimer model is no longer valid for the ionization channels and a close-coupling representation in terms of 'molecular ion + electron' is more appropriat e. This corresponds to a frame transformation defined by the projection coefficients:…”
Section: Theorymentioning
confidence: 99%
See 1 more Smart Citation
“…In the case of weak coupling, a perturbative solution of equation (2.3) can be obtained. This solution has been recently proven to be exact to second order, in the case of energy-independent electronic coupling (Ngassam et al 2003b). In the external zone, the 'B-region ' (Jungen and Atabek 1977) represented by large electron-core distances, the Born-Oppenheimer model is no longer valid for the ionization channels and a close-coupling representation in terms of 'molecular ion + electron' is more appropriat e. This corresponds to a frame transformation defined by the projection coefficients:…”
Section: Theorymentioning
confidence: 99%
“…Although it was applied with a great success to several diatomics (Schneider et al 2000b, Kokoouline et al 2001, Kokoouline and Greene 2003, its application to vibrational transitions, mainly to superelastic collisions, is very recent (Ngassam et al 2003a).…”
Section: Theorymentioning
confidence: 99%
“…[33] is not the K-matrix of MQDT, which includes an additional factor of −π.) First we introduce the diagonal quantum defect matrix µ, whose nonvanishing elements µ i are…”
Section: Combinationmentioning
confidence: 99%
“…This procedure applies in each -subspace, and results in a block-diagonal global interaction matrix. Starting from the interaction matrix V and from the zero-order Hamiltonian H 0 , we build the reaction K-matrix, which satisfies the Lippmann-Schwinger equation [25]:…”
Section: The Stepwise Mqdt-type Approach For Electron/molecular Catiomentioning
confidence: 99%