In this paper, the strong form factors and coupling constants of D s DK * and D s D * K * vertices are investigated within the three-point QCD sum rules method with and without the SU f (3) symmetry. In this calculation, the contributions of the quark-quark, quark-gluon, and gluongluon condensate corrections are considered. As an example of specific application of these coupling constants, the branching ratio of the hadronic decay B + → K * 0 π + is analyzed based on the one-particle-exchange which is one of the phenomenological models. In this model, B decays into a D s D * intermediate state, and then these two particles exchange a D(D * ) producing the final K * and π mesons. In order to compute the effect of these interactions, the D s DK * and D s D * K * form factors are needed.