Versuche zur Epimerisierung der cis‐trans‐isomeren 2,6‐Dimethyl‐2‐(4‐methoxy‐phenyl)‐cyclohexanone

Stereochemistry of the 2‐Aryl‐cyclohexanones. I. Analysis of the Configuration and Conformation of the cis‐trans‐Isomeric 2,6‐Dimethyl‐2‐aryl‐cyclohexan‐1‐ones by the Aid of their Oximes Desulfurization of the n‐butylthiomethylene ketone 6 with Raney nickel yields a mixture of trans‐ and cis‐stereoisomers 7 and 8, the conformations of which are 7A and 8B, respectively. While the ketone 7 gives rapidly and quantitatively the oxime 9, the isomer 8 reacts much more slowly to a mixture of 9 and 10. A detailed analysis of the configuration and conformation of the ketones 7 and 8 as well as the oximes 9 and 10 is given.

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Stereochemie der 2‐Aryl‐cyclohexanone. I. Konfigurations‐ und Konformationsanalyse der cis‐trans‐isomeren 2,6‐Dimethyl‐2‐aryl‐cyclohexan‐1‐one über ihre Oxime

Palitzsch¹,

Huneck

Fischer

1986

J. Prakt. Chem.

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Versuche zur Epimerisierung der cis‐trans‐isomeren 2,6‐Dimethyl‐2‐(4‐methoxy‐phenyl)‐cyclohexanone

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Stereochemie der 2‐Aryl‐cyclohexanone. I. Konfigurations‐ und Konformationsanalyse der cis‐trans‐isomeren 2,6‐Dimethyl‐2‐aryl‐cyclohexan‐1‐one über ihre Oxime

Stereochemie der 2‐Aryl‐cyclohexanone. I. Konfigurations‐ und Konformationsanalyse der cis‐trans‐isomeren 2,6‐Dimethyl‐2‐aryl‐cyclohexan‐1‐one über ihre Oxime

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