A series of amphiphilic ion exchange membranes (50PS–PBP-x) containing propyl sulfonic acid, long octadecyl side
chains, and piperidinium quaternary ammonium structures are designed
and prepared by the Menshutkin reaction of poly(biphenyl piperidinium)s
with sodium 3-bromopropanesulfonate and 1-bromooooctadecane. The surface
morphology and microphase separation structures of the amphiphilic
membranes are observed by scanning electron microscopy (SEM) and atomic
force microscopy (AFM), respectively. Their water uptake and swelling
ratio are in the range of 9.2–20.2 and 3.7–7.8%, respectively.
The area resistances and vanadium ion permeabilities for these membranes
are in the range of 0.35–0.51 Ω cm2 and 1.9
× 10–7–4.7 × 10–7 cm2 min–1, respectively. The vanadium
redox flow battery based on the representative 50PS–PBP-30
membrane also exhibits good performance. Its maximum energy efficiency
reaches 81.7% and does not obviously decline after 200 cycles of running.