Versatile Post‐functionalization of Polyoxometalate Platforms By Using An Unprecedented Range of Palladium‐Catalyzed Coupling Reactions

Abstract

Handy POMs: Several palladium-catalyzed coupling reactions have been applied to polyoxometalate post-functionalization. The feasibility of each reaction with one model substrate was investigated and each set of synthetic conditions was optimized to obtain full conversions and high purity hybrid compounds.

Tailor–made Covalent Organic‐Inorganic Polyoxometalate Hybrids: Versatile Platforms for the Elaboration of Functional Molecular Architectures

“…This allows having a unified functionalization strategy transposable to various platforms of different sizes, topologies and charges. More recently, we also extended the post‐functionalization to Mizoroki–Heck, Suzuki, Hiyama and Miyaura couplings, which broaden the range of post‐functionalization routes …”

A covalent polyoxomolybdate-based hybrid with remarkable electron reservoir properties

“…The iodo-aryl functionality provides a useful tool for post-functionalisation via organometallic cross coupling reactions. 17,20 A large number of POM-based hybrids have thus been synthesised. The potential of these covalent hybrids for various applications such as artificial photosynthesis, 21 molecular self-healing 19 and molecular electronics 15 has been explored.…”

The Hiyama Cross‐Coupling Reaction: New Discoveries

“…Finally, dimethyl‐2‐thienylvinylsilane was very efficient for the post‐functionalization of polyoxometalate platforms under palladium‐catalyzed coupling reactions 53…”