Abstract:High catalytic activities of Ru-PNP complexes in ionic liquid (IL) were obtained for the reversible hydrogenation of CO2 and dehydrogenation of formic acid (FA) under exceedingly mild conditions. The novel catalytic system relies on an unprecedented IL-promoted activation of CO2 and proceeds already at 25 ⁰C under a continuous flow of 1 bar of CO2/H2, leading to 14 mol% FA with respect to the IL, whereas a pressure of 40 bar of CO2/H2 (1:1) provides 126 mol% of FA/IL. The conversion of CO2 contained in imitate… Show more
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