The
recovery of uranium from low-level radioactive effluents (LLRE)
is of strategic significance for the sustainable development of nuclear
energy. However, the high salinity, massive coexisting nuclides, and
radioactivity of LLRE are the major challenges for selective uranium
extraction. Herein, a two-dimensional U(VI)-imprinted strategy is
developed for highly selective uranium extraction through one-step
fabrication of a specific U(VI)-imprinted cavity on silica lamellar.
Thanks to the two-dimensional structure of silica lamellar, the optimal
adsorbent possesses a high specific surface area of 497.7 m2 g–1 and abundant imprinted cavities with a phosphate
group. Thus, the adsorbent has an adsorption capacity of 224.2 mg
g–1 at 298 K, which is higher than most of the U(VI)-imprinted
adsorbents. As the temperature increases to 308 and 318 K, the adsorption
capacity gradually increases to 253.8 and 274.0 mg g–1, respectively. In addition, due to the great affinity to uranium
and stability of imprinted cavities, the adsorbent exhibits a good
salt tolerance of adsorption and a high selectivity for uranium against
other coexisting ions even after 6 adsorption–desorption cycles.
This work provides an efficient strategy for designing selective U(VI)
adsorbents for LLRE treatment, which is meaningful in environmental
and energy fields.