Levitated nanoparticles in vacuum, with their intrinsically
low
coupling to the environment, hold the promise of precision force sensing
and open new avenues for exploring macroscopic quantum physics. Ultimately,
the coherence of the levitated oscillator is limited by its blackbody
radiation emission and hence its internal temperature. Controlling
the internal temperature of a levitated object in vacuum poses a formidable
challenge, necessitating contactless cooling methods such as laser
refrigeration via anti-Stokes fluorescence. We report on a study exploring
the design and synthesis of nanoparticles that can enhance their laser
refrigeration efficiency. We developed lanthanide-doped nanocrystals
with an inert shell coating and compared their cooling performance
with that of bare nanocrystals while optically levitated. We found
that the core–shell design shows an improvement in the minimum
final temperature: about 31% of the core–shell nanoparticles
showed significant cooling compared to a minimal cooling effect for
12% of the bare nanoparticles. Furthermore, we measured a core–shell
nanoparticle cooling down to a temperature of 148 ± 4 K at 26
mbar in the underdamped regime. Our study is a first step toward engineering
nanoparticles that are suitable for achieving absolute (center of
mass and internal temperature) cooling in levitation, enabling novel
prospects for realizing macroscopic quantum superpositions.