A structural change between amorphous and crystalline
phase provides
a basis for reliable and modular photonic and electronic devices,
such as nonvolatile memory, beam steerers, solid-state reflective
displays, or mid-IR antennas. In this paper, we leverage the benefits
of liquid-based synthesis to access phase-change memory tellurides
in the form of colloidally stable quantum dots. We report a library
of ternary M
x
Ge1–x
Te colloids (where M is Sn, Bi, Pb, In, Co, Ag) and then showcase
the phase, composition, and size tunability for Sn–Ge–Te
quantum dots. Full chemical control of Sn–Ge–Te quantum
dots permits a systematic study of structural and optical properties
of this phase-change nanomaterial. Specifically, we report composition-dependent
crystallization temperature for Sn–Ge–Te quantum dots,
which is notably higher compared to bulk thin films. This gives the
synergistic benefit of tailoring dopant and material dimension to
combine the superior aging properties and ultrafast crystallization
kinetics of bulk Sn–Ge–Te, while improving memory data
retention due to nanoscale size effects. Furthermore, we discover
a large reflectivity contrast between amorphous and crystalline Sn–Ge–Te
thin films, exceeding 0.7 in the near-IR spectrum region. We utilize
these excellent phase-change optical properties of Sn–Ge–Te
quantum dots along with liquid-based processability for nonvolatile
multicolor images and electro-optical phase-change devices. Our colloidal
approach for phase-change applications offers higher customizability
of materials, simpler fabrication, and further miniaturization to
the sub-10 nm phase-change devices.