Abstract:Three precursors of group 11 metals, gold(I) 1,3-diisopropyl-imidazolidin-2ylidene hexamethyldisilazide, gold(I) tert-butyl-imino-2,2-dimethylpyrrolidinate, silver(I) tertbutyl-imino-2,2-dimethylpyrrolidinate were subjected to solution based NMR thermolysis studies. Rates of decomposition and order of reactivity were gathered by monitoring the disappearance of starting material. Two novel antimony compounds, trimethyl phosphine antimony (III) chloride and bistrimethyl phosphine antimony (III) chloride were sub… Show more
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