The
present investigation deals with the surface modification of
sub-micrometer boron particles with octadecyltrimethoxysilane (OTMS,
a silane compound) to improve the dispersion stability of boron particles
in liquid fuel. Characterizations of as-received and silane-coated
boron particles in terms of the particle size, morphology, surface
chemistry, ignition temperature, and oxidation profile have been conducted
using typical material characterization methods, such as scanning
electron microscopy, scanning transmission electron microscopy, X-ray
photoelectron spectroscopy, and thermogravimetric analysis (TGA).
The results show that the surfaces of as-received boron particles
have been successfully functionalized via a condensation reaction
of hydroxyl function groups (−OH) with OTMS molecules. The
capping of OTMS on the boron surface makes the particle stable against
air oxidation. The dispersion stabilities of OTMS-capped boron in
Jet A-1 at particle loadings of 1, 5, and 10% are found out to be
20, 18, and 2 h, respectively. Ignition and combustion characteristics
of as-received and silane-coated boron particles loaded in Jet A-1
at desired concentrations have been analyzed to understand the effect
of silane coating. TGA, true color flame images, and spectroscopic
results show that the burning process of OTMS-capped boron is slightly
delayed in comparison to as-received boron. The droplet diameter regression
profiles show smooth regression up to 70–80% of the droplet
lifetime with some intermittent puffing with disruptions at a later
stage in both of the particle cases. However, the intensity of disruption
is stronger in the case of OTMS-capped boron because of the formation
of a more compact shell inside the droplet as a result of the melting
of the OTMS layer (particularly toward the end of the droplet lifetime).
The micrographs of the combustion residue reveal that some tiny holes
are present on the residue surface in the case of as-received boron,
whereas multiple blow holes are there in the case of OTMS-capped boron.
A blanket of silicon seems to cover the particle surface, which makes
them stick together.