Vapor-Phase Loading of an Ionic Liquid into a Zeolitic Imidazolate Framework

Obst, Martin; Tietze, Max L.; Matavž, Aleksander; Rodríguez‐Hermida, Sabina; Marcoen, Kristof; Hauffman, Tom; Ameloot, Rob

doi:10.1021/acs.inorgchem.2c02615

Cited by 4 publications

(3 citation statements)

References 43 publications

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“…The process and setup of vapor-phase ship-in-bottle method for [Bmim]Br@ZIF-8 (c) and the reversibility of the [Bmim]Br loading on ZIF-8 by vapor-phase ship-in-bottle method (d). 85 Copyright 2022, American Chemical Society. and to provide feedback for rational design of novel IL-MOFs/ COFs.…”

Section: Interaction Mechanism Between Ils and Mofs/cofsmentioning

confidence: 99%

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Ionic Liquid-Functionalized Metal–Organic Frameworks/Covalent–Organic Frameworks for CO₂ Capture and Conversion

Chen,

Wang,

Zhang

et al. 2024

Ind. Eng. Chem. Res.

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CO 2 capture and conversion have garnered worldwide attention in view of the objective of sustainable development and carbon neutrality. Recently, ionic liquid-functionalized metal−organic frameworks (MOFs) or covalent−organic frameworks (COFs) (MOFs/COFs) offer a rising platform for the effective CO 2 separation from specific gas mixture and CO 2 conversion into value-added chemicals. Benefiting from the synergistic effect offered by ILs and MOFs/COFs, IL-MOFs/COFs exhibit better exceptional adsorption/catalytic performance than pristine MOFs/COFs or ILs. Herein, the review intends to establish a primary database for the recently emerging IL-MOFs/COFs in CO 2 capture and conversion, covering the functionalization strategies, interaction between ILs and MOFs/COFs, and the representative applications, aiding in the rational design and optimization of novel IL-MOFs/COFs with exceptional properties for real-world application. Along this line, CO 2 capture from different systems (CO 2 /N 2 , CO 2 /CH 4 , and CO 2 /C 2 H 2 ) and further conversion into multiproducts (cyclic carbonate, hydrocarbon, alcohol, and others), along with the mechanism insight into ILs and MOFs/COFs in such adsorption/catalytic processes are summarized and discussed. Furthermore, the challenges and prospects of IL-MOFs/COFs in such emerging and topical fields have been elaborated.

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Section: Interaction Mechanism Between Ils and Mofs/cofsmentioning

confidence: 99%

“…Copyright 2018, American Chemical Society. The process and setup of vapor-phase ship-in-bottle method for [Bmim]Br@ZIF-8 (c) and the reversibility of the [Bmim]Br loading on ZIF-8 by vapor-phase ship-in-bottle method (d) 85. Copyright 2022, American Chemical Society.…”

mentioning

confidence: 99%

Ionic Liquid-Functionalized Metal–Organic Frameworks/Covalent–Organic Frameworks for CO₂ Capture and Conversion

Chen,

Wang,

Zhang

et al. 2024

Ind. Eng. Chem. Res.

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“…In recent years, ionic liquids (ILs) have been widely used in preparation of inorganic materials, , nanomaterials, , perovskites, and metal organic frameworks − due to their good solubility, good thermal stability, and high viscosity. , ILs are potential candidates to be incorporated of metal clusters, which can either serve as internal templates to be encapsulated within the metal clusters or exist as large counter anions for metal clusters. A few studies on ILs-assisted synthesis of Au and Ag clusters are known to date, and ILs are used as binders or surface modifiers. − However, the advantages of ILs as anion templates and anion ligands in controllable synthesis of metal clusters, especially in Cu(I)H clusters, have not been fully addressed.…”

Section: Introductionmentioning

confidence: 99%

Ionic Liquids-Driven Cluster-to-Cluster Conversion of Polyhydrido Copper(I) Clusters Cu₇H₅ to Cu₈H₆ and Cu₁₂H₉

Huang,

Chen,

et al. 2023

Inorg. Chem.

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Although ionic liquids (ILs) are of prime interest for the synthesis of various nanomaterials, they are scarcely utilized for the polyhydrido copper(I) [Cu(I)H] clusters. Herein, two air-stable Cu(I)H clusters, [Cu 8 H 6 (dppy) 6 ](NTf 2 ) 2 (Cu 8 H 6 ) and {Cu 12 H 9 (dppy) 6 [N(CN) 2 ] 3 } (Cu 12 H 9 ), are synthesized in high yields for the first time from the ILs-driven conversion of an unprecedented cluster [Cu 7 H 5 (dppy) 6 ](ClO 4 ) 2 (Cu 7 H 5 ) by a facile three-layers diffusion crystal (TLDC) method, strategically introducing IL-NTf 2 and IL-N(CN) 2 as two types of unusual interfacial crystallized templates, respectively. Their structures are fully characterized by various spectroscopic methods and X-ray crystallography, which shows that the anion of IL plays an important role as an anion template and an anion ligand in controlling the structural conversion of Cu(I)H clusters. Their photophysical properties are also investigated, and it is found that all reported clusters exhibit red luminescence with λ em ranging from 600 to 690 nm.

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A magnetic pore-confined catalyst with ionic liquids supported on MOFs for the synthesis of aryl-oxazolidinones: design, performance, and recyclability

Chong,

Li,

Zhao

et al. 2024

Chemical Engineering Journal

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Vapor-Phase Loading of an Ionic Liquid into a Zeolitic Imidazolate Framework

Cited by 4 publications

References 43 publications

Ionic Liquid-Functionalized Metal–Organic Frameworks/Covalent–Organic Frameworks for CO₂ Capture and Conversion

Ionic Liquid-Functionalized Metal–Organic Frameworks/Covalent–Organic Frameworks for CO₂ Capture and Conversion

Ionic Liquids-Driven Cluster-to-Cluster Conversion of Polyhydrido Copper(I) Clusters Cu₇H₅ to Cu₈H₆ and Cu₁₂H₉

A magnetic pore-confined catalyst with ionic liquids supported on MOFs for the synthesis of aryl-oxazolidinones: design, performance, and recyclability

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Vapor-Phase Loading of an Ionic Liquid into a Zeolitic Imidazolate Framework

Cited by 4 publications

References 43 publications

Ionic Liquid-Functionalized Metal–Organic Frameworks/Covalent–Organic Frameworks for CO2 Capture and Conversion

Ionic Liquid-Functionalized Metal–Organic Frameworks/Covalent–Organic Frameworks for CO2 Capture and Conversion

Ionic Liquids-Driven Cluster-to-Cluster Conversion of Polyhydrido Copper(I) Clusters Cu7H5 to Cu8H6 and Cu12H9

A magnetic pore-confined catalyst with ionic liquids supported on MOFs for the synthesis of aryl-oxazolidinones: design, performance, and recyclability

Contact Info

Product

Resources

About

Ionic Liquid-Functionalized Metal–Organic Frameworks/Covalent–Organic Frameworks for CO₂ Capture and Conversion

Ionic Liquid-Functionalized Metal–Organic Frameworks/Covalent–Organic Frameworks for CO₂ Capture and Conversion

Ionic Liquids-Driven Cluster-to-Cluster Conversion of Polyhydrido Copper(I) Clusters Cu₇H₅ to Cu₈H₆ and Cu₁₂H₉