Vapor-liquid equilibria for binary mixtures of carbon dioxide and fatty acid ethyl esters

Lipase‐catalyzed esterification of stearic acid with ethanol, and hydrolysis of ethyl stearate, near the critical point in supercritical carbon dioxide

“…The solubilities of SA, water, and ES in SCCO 2 were calculated from our previous data (24), data by Wiebe and Gaddy (27), and data by Bharath et al (28), respectively.…”

Revision and summary of the group contribution equation of state parameter table: Application to edible oil constituents

“…10. Experimental and calculated solubility in CO 2 of ethyloleate ( )) at 323 K [36], squalene ( ) [31], ␣-tocopherol ( ) [33] and triolein ( ) [35] at 313 K, oleic acid (*) at 333 K [38], monoolein ( ) at 333 K and diolein (᭹) at 323 K [32]. Solid lines: GC-EoS correlation.…”

“…9. Experimental and calculated equilibrium constant (k eq = weight fraction in vapor phase/weight fraction in liquid phase) for ethyloleate at (×) 313 K, (+) 323 K and (*) 333 K [36], triolein at (᭹) 313 K [35] and ( ) 333 K [37], ␣-tocopherol at ( ) 313 K [33] and ( ) 333 K [34], squalene at ( ) 313 K [31] in binary mixture with CO 2 . Solid lines: GC-EoS correlation.…”

Solubility assessment of castor ( Ricinus communis L) oil in supercritical CO 2 at different temperatures and pressures under dynamic conditions

“…Such fluid-liquid equilibrium data for fatty acid methyl esters and fatty acid ethyl esters in SC-CO 2 have been measured by Inomata et al (1989) and Bharath et al (1989). Fluid-solid equilibria of fatty acids and triglycerides in SC-CO 2 were studied by Chrastil (1982) and Bamberger et al (1988).…”