Vapor-liquid equilibria for .alpha.-pinene or .beta.-pinene with anisole

Measurements, Correlations, and Modified UNIFAC Predictions of Isobaric Vapor–Liquid Equilibrium Data for the Binary System of Dimethyl Carbonate + Anisole at Different Pressures

“…The pure component bubble temperatures of anisole and DMC at different pressures, measured in this study, are compared with the computed values of the Antoine equation (using constants reported in Table ) in Figure . This figure also shows the experimental data of pure components reported by other researchers at different pressures. − Figure a clearly indicates that boiling point of anisole matches very well at all five pressures with the predicted and other researcher’s data. − Figure b illustrates the % deviation of pure anisole temperature from Antoine’s equation and other researcher’s data, − and the present study indicates a maximum deviation of 0.46%. Further, Figure c shows the boiling point of pure DMC at all five pressures with the predicted and other researchers data, − and the % deviation of pure DMC temperature from Antoine’s equation and other researcher’s data, − as depicted in Figure d, at different pressures show that three of the experimental data points match well with the predictions as estimated within 0.43% deviation, whereas a bit more deviations of 0.78 and 0.93% are observed at 73.33 and 59.99 kPa, respectively.…”

“…Further, the properties of densities, refractivity, excess molar volumes, and deviations in molar refractivity were also determined at 298.15 K for the binary systems of methanol (1) + DMC or anisole (2). VLE data for some binary mixtures consisting of either DMC or anisole with other components have been reported. − Recently, Song et al have reported isobaric VLE data for the binary mixtures of DMC + dimethyl sulfoxide, DMC + anisole, DMC + diethyl oxalate, and methanol + diethyl oxalate at 101.3 kPa. However, for the binary system of DMC–anisole, isobaric, VLE data have not been reported specifically at 33.33, 46.66, 59.99, 73.33, and 94.66 kPa.…”

Weaving a web of reliable thermochemistry around lignin building blocks: phenol, benzaldehyde, and anisole

“…3 Temperature dependence of vapour pressures for the anisole: blue round-transpiration [73]; •-ebulliometry [66]; ○-ebulliometry [65]; red triangle-ebulliometry [74]; purple square-calorimetry [67]; ▲-ebulliometry [70]; green round-ref. [42]; yellow round-ebulliometry [71]; red round-ebulliometry [69]; yellow square-ref. [40].…”

“…3. The primary vapour pressure data [40,42,58,[64][65][66][67][68][69][70][71][72][73][74] are collected in Table S4. We approximated them using the Clark-Glue equation, in order to derive thermodynamics functions of va p o r i s a t i o n ( s e e Ta b l e 1 0 ) .…”

“…Compared to phenol and benzaldehyde, the vaporisation thermodynamics of anisole was investigated not only by the indirect methods (from vapour pressure temperature dependence) [40,42,58,[64][65][66][67][68][69][70][71][72][73][74], but also directly using the vaporisation calorimetry [5,64,67,68]. It has turned ( 10).…”