Vanadium silicon-oxyfluoride nanowires for lithium storage systems: A perfect synergy for dynamic simple spot synthesis

Kirubakaran, Kiran Preethi; Senthil, Chenrayan; Raghu, S.; Priyadarshini, Marimuthu; Kamalakannan, Shanmugasundaram; Prakash, M.; Lee, Chang Woo; Vediappan, Kumaran

doi:10.1016/j.mseb.2021.115164

Cited by 3 publications

(1 citation statement)

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“…Increasing the operating voltage of ASCs via the development of metal-ion hybrid battery capacitors (MHCs) consisting of a capacitor-type cathode and a battery-type anode (such as Li-, K-, Na-, or Zn-metal) is considered an effective strategy to improve the overall energy density. 10–15 Among the various MHCs, aqueous Zn-ion hybrid capacitors (ZHCs) are the most promising owing to the abundant natural resources of Zn metal, high theoretical capacity (820 mA h g −1 ), lower redox potential (than normal hydrogen electrodes), outstanding safety, and environmental benignity. 16–21 Particularly, studies have demonstrated the simplicity and economic viability of ZHCs composed of activated porous carbon (PC) as a cathode, Zn foil as an anode, and aqueous Zn-electrolyte for energy storage via adsorption/desorption (ads/des), deposition/stripping and precipitation/dissolution mechanisms, respectively.…”

Section: Introductionmentioning

confidence: 99%

A low cost Zn²⁺/I⁻ redox active electrolyte for a high energy and long cycle-life zinc hybrid battery–capacitor

Selvaraj,

Sambandam,

Kim

et al. 2023

J. Mater. Chem. A

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Section: Introductionmentioning

confidence: 99%

A low cost Zn²⁺/I⁻ redox active electrolyte for a high energy and long cycle-life zinc hybrid battery–capacitor

Selvaraj,

Sambandam,

Kim

et al. 2023

J. Mater. Chem. A

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Progress in doping and crystal deformation for polyanions cathode based lithium-ion batteries

Awasthi,

Moharana,

Kumar

et al. 2024

Nano Materials Science

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Sensitive mode investigations of lithium-ion cells with tavorite-type LiVXO4F (X = B, Si) as cathodes with stable cycling in low temperature operations

Kirubakaran

Senthil

Kumaresan

et al. 2022

Applied Physics Letters

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Li-ion battery cathodes appear to be a significant factor affecting the total amount of energy delivered and the cost of the battery systems. LiVXO4F (X = B, Si), a polyanionic-based tavorite structure, is investigated as a cathode for Li-ion batteries and its capability to endure in sensitive mode operations, i.e., at temperatures of approximately 55 and −10 °C. Due to the near-freezing point at the atomic level and the absence of kinetic energy, a battery system operating at a lower temperature is theoretically expected to perform inferior. On the contrary, Vanadium boron oxyfluoride (VBF) has better electrochemical properties because of its tightly packed covalent bond, which produced structural stability at low temperature activities. This intriguing feature appears to hold promise for its use in advanced rechargeable battery systems in low-temperature areas and cold storage devices. This might pave the path for future energy storage and conversion devices to use neoteric tavorite structured electrodes.

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Vanadium silicon-oxyfluoride nanowires for lithium storage systems: A perfect synergy for dynamic simple spot synthesis

Cited by 3 publications

References 48 publications

A low cost Zn²⁺/I⁻ redox active electrolyte for a high energy and long cycle-life zinc hybrid battery–capacitor

A low cost Zn²⁺/I⁻ redox active electrolyte for a high energy and long cycle-life zinc hybrid battery–capacitor

Progress in doping and crystal deformation for polyanions cathode based lithium-ion batteries

Sensitive mode investigations of lithium-ion cells with tavorite-type LiVXO4F (X = B, Si) as cathodes with stable cycling in low temperature operations

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Vanadium silicon-oxyfluoride nanowires for lithium storage systems: A perfect synergy for dynamic simple spot synthesis

Cited by 3 publications

References 48 publications

A low cost Zn2+/I− redox active electrolyte for a high energy and long cycle-life zinc hybrid battery–capacitor

A low cost Zn2+/I− redox active electrolyte for a high energy and long cycle-life zinc hybrid battery–capacitor

Progress in doping and crystal deformation for polyanions cathode based lithium-ion batteries

Sensitive mode investigations of lithium-ion cells with tavorite-type LiVXO4F (X = B, Si) as cathodes with stable cycling in low temperature operations

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A low cost Zn²⁺/I⁻ redox active electrolyte for a high energy and long cycle-life zinc hybrid battery–capacitor

A low cost Zn²⁺/I⁻ redox active electrolyte for a high energy and long cycle-life zinc hybrid battery–capacitor