This study investigated catalytic reforming, which is
a thermochemical
process, as a pioneering method to treat biogas slurry (wastewater
from biogas plants) and generate hydrogen. Experimental validation
for treating biogas slurries from digested cattle manure, fish intestine,
and wheat straw was performed on Ni/α-Al2O3 catalyst. The results showed that the total organic carbon, total
nitrogen, and PO4
3– ion contents in biogas
slurry could be reduced by 98.69, 98.01, and 99.32%, respectively.
The highest hydrogen yield was obtained in the treatment of biogas
slurry from digested cattle manure at 750 °C, in which the hydrogen
yield and hydrogen concentration were 13.85 L
hydrogen/L
BS and 79.77 vol %, respectively.
Changes in the crystalline phase and structure of the catalyst were
observed during catalytic reforming of biogas slurry. Active metal
oxidization and carbon deposition were likely to be important factors
affecting catalytic stability. The mass flow evaluation verified the
hydrogen generation potential by the catalytic reforming of biogas
slurry, which was close to the methane generation capability of the
upstream biogas plant. However, additional effort is required to address
the high energy consumption of this method. These findings provide
fundamental knowledge about the potential of applying thermochemical
techniques to treat and utilize high total organic carbon-containing
wastewaters.