Valorization of furfural using ruthenium (II) complexes containing phosphorus-nitrogen ligands under homogeneous transfer hydrogen condition

Parra-Melipán, Sebastián; López, Vicente Fidel; Moya, Sergio A.; Valdebenito, Gonzalo; Aranda, Braulio; Aguirre, Pedro

doi:10.1016/j.mcat.2021.111729

Cited by 3 publications

(1 citation statement)

References 44 publications

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“…The use of Lewis acid catalysis in this regard [34][35][36][37][38][39] played a significant role, which also suppressed the epimerization in the case of chiral molecules. Among the various Lewis acid catalysts such as ytterbium triflate, ZrO 2 , Cu(OT) 2 , MgBr 2 , LiBr, AlCl 3 , Fe and Ru catalysts have gained attention [40][41][42][43].…”

Section: Review Modernization Of the Cannizzaro Reactionmentioning

confidence: 99%

Synthetic applications of the Cannizzaro reaction

Chatterjee,

Mondal,

Bera

2024

Beilstein J. Org. Chem.

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The Cannizzaro reaction has emerged as a versatile synthetic tool for the construction of functionalized molecules. Dating back to the 19th century, this reaction, though initially used for the synthesis of an alcohol and acid functionality from aldehydes, has henceforth proven useful to generate diverse molecular entities using both intermolecular and intramolecular synthetic strategies. Immense applications in the synthesis of hydroxy acids and esters, heterocycles, fused carbocycles, natural products, and others with broad substrate scope have raised profound interest from methodological and synthetic standpoints. The ongoing development of reagents, solvents, and technologies for the Cannizzaro reaction reflects the broader trend in organic synthesis towards more sustainable and efficient practices. The focus of this review is to highlight some recent advances in synthetic strategies and applications of the Cannizzaro reaction towards the synthesis of potentially useful molecules.

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Section: Review Modernization Of the Cannizzaro Reactionmentioning

confidence: 99%

Synthetic applications of the Cannizzaro reaction

Chatterjee,

Mondal,

Bera

2024

Beilstein J. Org. Chem.

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Homogeneous Ruthenium catalyzed Hydrogenation of Furanoate Esters and Ether‐containing aliphatic Esters into primary Alcohols

Saudan

Quintaine

2023

ChemCatChem

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Furanoate esters have been hydrogenated successfully with ruthenium complexes bearing tetradentate ligands in high yield, high selectivity and with a low catalyst loading. The catalysts and the reaction conditions described herein enabled the facile reduction of a variety of substituted 2-and 3-furanoate esters, with the latter being never reduced before under catalytic hydrogenation conditions. Furthermore, several well-defined ruthenium complexes were evaluated and compared, with bis-imino complexes being the most versatile in terms of reactivity and selectivity. www.chemcatchem.org

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Efficient reductive etherification of furfural into furfuryl ethyl ether on Pd/Nb2O5 nanomaterials

Zhang

Yue

et al. 2022

Reac Kinet Mech Cat

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Valorization of furfural using ruthenium (II) complexes containing phosphorus-nitrogen ligands under homogeneous transfer hydrogen condition

Cited by 3 publications

References 44 publications

Synthetic applications of the Cannizzaro reaction

Synthetic applications of the Cannizzaro reaction

Homogeneous Ruthenium catalyzed Hydrogenation of Furanoate Esters and Ether‐containing aliphatic Esters into primary Alcohols

Efficient reductive etherification of furfural into furfuryl ethyl ether on Pd/Nb2O5 nanomaterials

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