Validation of a multiresidue method for the determination of pesticides in honeybees by gas chromatography

Martel, Anne‐Claire; Mangoni, Patrick; Gastaldi-Thiéry, Cristina

doi:10.1080/03067319.2018.1426754

Cited by 3 publications

(3 citation statements)

References 16 publications

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“…Currently, the classical chemical methods for pesticide residue detection include high-performance liquid chromatography (HPLC), gas chromatography (GC), gas chromatography-mass spectrometry (GC-MS), and liquid chromatography-mass spectrometry (LC-MS). [6][7][8][9] However, classical chemical methods are time-consuming and need expensive equipment, complex pretreatment, and specialized 1 College of Software, Jiangxi Agricultural University, Nanchang, China 2 College of Engineering, Jiangxi Agricultural University, Nanchang, China 3 College of Food Science and Engineering, Jiangxi Agricultural University, Nanchang, China 4 School of Chemistry and Food Science, Nanchang Normal University, Nanchang, China personnel. 10 Surface-enhanced Raman spectroscopy (SERS) is a rapid detection technique with convenient operation and high sensitivity and has been extensively applied for biological analysis, medical detection, environmental monitoring, cultural relic protection, and pesticide residues detection.…”

Section: Introductionmentioning

confidence: 99%

Exploring Surface-Enhanced Raman Spectroscopy (SERS) Characteristic Peaks Screening Methods for the Rapid Determination of Chlorpyrifos Residues in Rice

Xiong

Huang

et al. 2022

Appl Spectrosc

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Surface-enhanced Raman spectroscopy (SERS) coupled with characteristic peaks screening methods was developed for analyzing chlorpyrifos (CM) pesticide residues in rice. Au nanoparticles (AuNPs) were prepared as Raman signal enhancement. MgSO4, Primary secondary amine (PSA) and C18 were employed to purify the rice extraction. Successive projections algorithm (SPA) was performed to identify the optimal characteristic peaks of CM in rice from full Raman spectroscopy. Support vector machine (SVM) and partial least squares (PLS) were implemented to investigate the quantitative analysis models. The results demonstrated that six raman peaks such as 671, 834, 1016, 1114, 1436 and 1444 cm-1 were selected by SPA and SVM model had better performance using six peaks (only 0.92% of the full spectra variables) with R2p = 0.97, RMSEP = 2.89 and RPD = 4.26. And the experiment time for a sample was accomplished within 10 min. Recovery for 5 unknown concentration samples was 97.45 ∼ 103.96%. And T-test results also displayed no obvious differences between the measured value and the predicted value. The study stated that the SERS combined with characteristic peaks screening methods can be applied to rapidly monitor the chlorpyrifos residue in rice.

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Section: Introductionmentioning

confidence: 99%

Exploring Surface-Enhanced Raman Spectroscopy (SERS) Characteristic Peaks Screening Methods for the Rapid Determination of Chlorpyrifos Residues in Rice

Xiong

Huang

et al. 2022

Appl Spectrosc

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“…Because of the weak polarity, moderate boiling point and easy gasification, pyrethroid pesticides are typically detected using gas chromatography (GC). Now, many methods have been developed to analyze pyrethroid pesticides, mainly including gas chromatographyelectron-capture detector (GC-ECD) [7], GC coupled to mass spectrometry (GC/MS or GC-MS/MS) [8,9], high-performance liquid chromatography-mass spectrometry (HPLC-MS/MS) [10].…”

Section: Introductionmentioning

confidence: 99%

Research and Application of In Situ Sample-Processing Methods for Rapid Simultaneous Detection of Pyrethroid Pesticides in Vegetables

et al. 2022

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A novel rapid and cost-effective pre-processing method for the simultaneous determination of pyrethroid pesticides in vegetables has been developed and validated. The process of pesticide extraction was carried out by the QuEChERS (quick, easy, cheap, effective, rugged and safe) method combined with filtration by filter paper, and cleanup was carried out by the multi-plug-filtration-cleanup (m-PFC) method with no centrifuge program during the whole process. The pre-processing method is optimized for gas chromatography (GC). The process is convenient and time saving, requiring just a few seconds per sample. The recovery rate (70–120%), limit of detection (0.0001–0.007 mg/kg), precision (0.2–9.3%) and accuracy for each analyte were determined in 10 representative vegetables with good results. Finally, the feasibility of the developed method was further confirmed by the successful determination of pyrethroid-pesticide residues in pyrethroid-containing practical samples within the processing method coupled with thin-layer chromatography and a colloidal-gold test strip.

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“…Nearly 150 pesticides have been detected in hive products and most of them are acaricides. The residue accumulation in the hive products were in increased gradient from honey, pollen and bee wax (Martel et al, 2018;Mullin et al, 2010). In hive products, organochlorine (Blasco et al, 2003), neonicotinoids (Woodcock et al, 2017), organophosphate (Blasco et al, 2003) and other groups (acaricides and fungicides) (Chauzat et al, 2006) were reported.…”

mentioning

confidence: 97%

Pesticide Residue Analysis in Hive Products of <i>Apis cerana indica</i> F. from Tamil Nadu, India

Usharani,

Suresh

et al. 2023

IJE

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Honey and pollen collected from experimental fields in Kutladampatti village and farmer’s field from different locations of Tamil Nadu were analysed for the presence of pesticide residues in modified QuEChERs method which showed the coefficient of determination (R2) of 0.9939, 0.9919, 0.9869, 0.9803, 0.9981, 0.9918 and 0.9824 for chlorpyrifos, fipronil, lambda cyhalothrin, profenofos, imidacloprid, flubendiamide and thiamethoxam respectively. The method adopted in this experiment resulted in LOQ of 0.0036, 0.0057, 0.0027, 0.0027, 0.0032, 0.0041 and 0.0044 μg/g and LOD of 0.0011, 0.0017, 0.0008, 0.0008, 0.0009, 0.0012 and 0.0013 for chlorpyrifos, fipronil, lambda cyhalothrin, profenophos, imidacloprid, flubendiamide and thiamethoxam respectively. Recovery of the method was recorded as 96.33% for chlorpyrifos spiked with 0.1 μg/ g in honey while fipronil 0.1 μg/ g spiked honey samples recorded the maximum recovery of 102.33%. Lambda cyhalothrin recorded a maximum recovery of 98.67% in honey when spiked with 0.1 μg/ g of pesticide whereas Imidacloprid recorded a maximum recovery of 98.42% in honey when spiked with 0.1 μg/g of pesticide. Profenofos recorded with a maximum recovery of 103.33% in pollen sample spiked with 0.1 μg/ g. Flubendiamide recorded a maximum recovery of 99.67% in honey when spiked with 0.5 μg/ g of pesticide and thiamethoxam recorded 101.67% recovery in 0.1 μg/g spiked honey sample. The modified QuEChERS method recorded reduced matrix effect compared to conventional QuEChERS method. No residue of insecticidal chemicals was found in any of the samples collected from the experimental plots and farmer’s holdings as well.

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Validation of a multiresidue method for the determination of pesticides in honeybees by gas chromatography

Cited by 3 publications

References 16 publications

Exploring Surface-Enhanced Raman Spectroscopy (SERS) Characteristic Peaks Screening Methods for the Rapid Determination of Chlorpyrifos Residues in Rice

Exploring Surface-Enhanced Raman Spectroscopy (SERS) Characteristic Peaks Screening Methods for the Rapid Determination of Chlorpyrifos Residues in Rice

Research and Application of In Situ Sample-Processing Methods for Rapid Simultaneous Detection of Pyrethroid Pesticides in Vegetables

Pesticide Residue Analysis in Hive Products of <i>Apis cerana indica</i> F. from Tamil Nadu, India

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