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Mikheikin, I. D.; Kuznetsov, M.; Махонина, Е. В.; Pervov, V. S.

doi:10.1023/a:1018807217179

Cited by 9 publications

(9 citation statements)

References 2 publications

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“…Theoretical analysis 64,65 confirmed the possibility of selforganisation of suprastructures from structures incommensurate along one crystallographic direction. Mechanisms of this selforganisation were proposed in the studies.…”

Section: Main Concepts and Objects Of Inorganic Supramolecular Chemistrymentioning

confidence: 77%

“…Mechanisms of this selforganisation were proposed in the studies. 64,65 The results of these investigations are briefly surveyed in the next section. Here it should be noted that (as will be demonstrated below) a consideration of eutectics, which, in the limiting case, are incommensurate along all three crystallographic directions, in terms of supramolecular chemistry allows one to answer many questions and eliminate unclear facts, which we have mentioned in the discussion of the available concepts of eutectics.…”

Section: Main Concepts and Objects Of Inorganic Supramolecular Chemistrymentioning

confidence: 99%

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Supramolecular ensembles in eutectic alloys

Pervov¹,

Mikheikin²,

Махонина³

et al. 2003

Russ. Chem. Rev.

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The main concepts of the theory of eutectics are The main concepts of the theory of eutectics are analysed. The most essential results of investigations on eutectic analysed. The most essential results of investigations on eutectic alloys of inorganic compounds are surveyed. Evidence in favour alloys of inorganic compounds are surveyed. Evidence in favour of the supramolecular concept of eutectics is presented. This of the supramolecular concept of eutectics is presented. This concept takes into account interactions of incommensurate sub-concept takes into account interactions of incommensurate substructures and gives an insight into the mechanisms of formation structures and gives an insight into the mechanisms of formation of supramolecular eutectic assemblies in boundary regions (`non-of supramolecular eutectic assemblies in boundary regions (`nonautonomous phases'). Using the static one-dimensional Fren-autonomous phases'). Using the static one-dimensional Frenkel ± Kontorova model for finite systems, it is shown that the kel ± Kontorova model for finite systems, it is shown that the consideration of these mechanisms in terms of supramolecular consideration of these mechanisms in terms of supramolecular chemistry simplifies analysis of the behaviour of inorganic eutectic chemistry simplifies analysis of the behaviour of inorganic eutectic systems in the course of crystallisation under conditions both close systems in the course of crystallisation under conditions both close to and far from equilibrium, including crystallization upon to and far from equilibrium, including crystallization upon quenching and under external actions. The supramolecular con-quenching and under external actions. The supramolecular concept bridges gaps between the definitions `compound', `eutectic' cept bridges gaps between the definitions `compound', `eutectic' and `solution' in physicochemical analysis. The bibliography and `solution' in physicochemical analysis. The bibliography includes 83 references. includes 83 references.

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Section: Main Concepts and Objects Of Inorganic Supramolecular Chemistrymentioning

confidence: 77%

Section: Main Concepts and Objects Of Inorganic Supramolecular Chemistrymentioning

confidence: 99%

Supramolecular ensembles in eutectic alloys

Pervov¹,

Mikheikin²,

Махонина³

et al. 2003

Russ. Chem. Rev.

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“…Эвтектические супермолекулярные ансамбли формируются как неавтономные фазы, т.е. фазы, образующиеся вблизи контактной поверхности взаимодействующих субструктур [34][35][36][37].…”

Section: супрамолекулярные концепции в теории эвтектикunclassified

“…Существование таких фаз подтверждено литературными данными, в том числе экспериментальными результатами авторов работ [32,33]. Механизмы самоорганизации таких ансамблей обсуждены с привлечением одномерной статической модели Френкеля-Конторовой [34]. В качестве параметров задачи в расчетах был использован параметр несоразмерности подсистем, их подробности даны в [34].…”

Section: супрамолекулярные концепции в теории эвтектикunclassified

“…Анализ работ [14,[20][21][22][23][32][33][34][35][36][37], посвященных строению и свойствам эвтектических сплавов, позволяет считать, что предполагаемая концепция соответствует многочисленным феноменологическим данным, но противоречит классическим теоретическим представлениям эвтектик как механических смесей [1][2][3][4][5][6], что необходимо пересмотреть. В этом отношении представляет интерес рассмотрение эвтектик на основе Для достижения данной цели необходимо было решить следующие задачи: вырастить кристаллы эвтектики, изучить морфологию и состав поверхности фаз методом атомно-силовой микроскопии (АСМ) и рентгеновской дифрактометрии (РД), исследовать термоэлектрические параметры эвтектики.…”

Section: супрамолекулярные концепции в теории эвтектикunclassified

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