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Reprint of: Crystalline and liquid vapour pressures of the four p-monohalophenols: A thermodynamic study of their phase transitions

“…Its enthalpy of fusion derived from the static vapour pressure results is close to the result derived from the DSC analysis. The temperature of fusion of p-chlorophenol, determined by calorimetric measurements is 0.5 K higher than the value derived from the intersection of the vapour pressure equations, and 1 K higher than the ones published in literature [26,27]. The results of enthalpy of fusion determined indirectly and calorimetrically are equal within the experimental uncertainty and are in excellent agreement with the literature results [26,27].…”

“…The temperature of fusion of p-chlorophenol, determined by calorimetric measurements is 0.5 K higher than the value derived from the intersection of the vapour pressure equations, and 1 K higher than the ones published in literature [26,27]. The results of enthalpy of fusion determined indirectly and calorimetrically are equal within the experimental uncertainty and are in excellent agreement with the literature results [26,27]. For p-bromophenol, the temperature of the triple point is 1.4 K lower than the temperature of fusion obtained from DSC measurements and ca.…”

Thermochemistry of Chlorobenzenes and Chlorophenols: Ambient Temperature Vapor Pressures and Enthalpies of Phase Transitions

“…The reference temperature T 0 = 298.15 K has been chosen. Values of C p (or C p ) have been derived from the experimental , isobaric molar heat capacities of liquid ( ) or solid ( ) chlorophenols according to a procedure developed by Chickos and Acree , (see Table ). In order to assess the uncertainty of the vaporization enthalpy, the experimental data were approximated with the linear equation ln( ) = f ( T -1 ) using the method of least-squares.…”

Calculation of the Isobaric Heat Capacities of the Liquid and Solid Phase of Organic Compounds at 298.15K by Means of the Group-Additivity Method

“…A number of new experimental C p data have been published for saturated and unsaturated hydrocarbons, especially for bicyclo [ [14], and adamantane [15]. In addition, further C p values have been found for the amines hexamethylenetetramine [15], tetra-N-phenylbenzidine and 4,4 -bis (N-carbazolyl)-1,1 -biphenyl [16], 1,3,5-triazine [17], the ethers 1,3,5-trioxane [17], diethylene glycol n-pentyl ether [18], triethylene glycol monopentyl ether [19] and diphenyl ether [20], several alcohols and aldehydes [21], derivatives of glycidol [22], carboxylic acids [23,24], aliphatic esters [24][25][26][27], benzoates [28], haloalkanes [29,30], haloaromatics [31,32], thio ethers, sulfones and sulfoxides [33,34], alkanolamines, [35][36][37] and nitriles [38] For several compounds, more recent publications have been found the following: 4-ethylmorpholine [39], methionine [40], theophylline, and caffeine [41], as well as for (-)-menthone, (+)-pulegone, and (-)-isopulegol [42]. Beyond these, experimental C p values of a number of new compounds have been published: namely 3-amino-4-amidoximinofurazan [43], 3-fluoro-5-(3-pyridinyloxy)-benzenamine and N- [46], eugenol and (+)-carvone [47], indapamide [48], and the explosives EDNH and DNTA [49].…”