Abstract. Branched glycerol dialkyl glycerol tetraethers (brGDGTs) are
useful molecular indicators for organic carbon (OC) sources and the
paleoenvironment. Their application in marine environments, however, is
complicated because of a mixed terrestrial and marine source. Here, we
examined brGDGTs in sediments from the Mariana Trench, the deepest ocean
without significant terrestrial influence. Our result shows a strong
predominance of hexamethylated 6-methyl brGDGT (IIIa′) (73.40±2.39 % of total brGDGTs) and an absence of 5-methyl brGDGTs, different
from previously reported soils and marine sediments that comprised both
5-methyl and 6-methyl brGDGTs. This unique feature, combined with high
δ13COC (-19.82±0.25 %), low OC∕TN ratio (6.72±0.84), low branched and isoprenoid tetraether (BIT) index (0.03±0.01), and high acyclic hexa- ∕ pentamethylated brGDGT ratio (7.13±0.98), support that brGDGTs in the Mariana Trench sediments are
autochthonous rather than terrestrial products. The compiling of literature
data shows that the enhanced fractional abundance of hexamethylated 6-methyl
brGDGTs is a common phenomenon in continental margins when the marine
influence was intensified. The cross plot of acyclic hexa- ∕ pentamethylated
brGDGT ratio and fractional abundance of brGDGT IIIa′ provide a novel
approach to distinguish terrestrial and marine-derived brGDGTs.