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UDC 666.92:[669.!84~225o~66~ 2~At present torch guniting, which was developed in the 70~s in the US$~ ~l~ ~ ~s ~eimg improved in two directions. The first is intensification of the processes of combustion of the flame for the purpose of increasing the life of the periclase coatings [I], and the sec ~ ond is conversion to guniting with inexpensive and readily available materials (primarily lime) for partial or complete replacement of periclase powders in guniting mixtures [5,6].The first direction is accomplished in the following manner.By selecting the forms of fuel [I, 7] or by changing the design of the heads of multinozzle guniting guns [4,8] a reduction in coating porosity is obtained.However, with packing the periclase coating starts to spall and therefore additional measures for elimination of thermal failure of gunited coatings become necessary.These include additions to the guniting mixture of slags and oxides of iron [i] or aluminum [2] or guniting with thin layers [3]. The latter measure is not always possible under the conditions of organization of work in converter shops, and additions of oxides lead to a reduction in the slag resistance of the applied layers. Until now there have been no examples of a positive solution of this problem on a production scale~The second direction in improvement in torch guniting is accomplished by application to the working surface of converter linings of refractory slag-forming coatings.This process was developed by the All-Union Institute for Refractories and by the Azov Steel, Western Siberia, and Cherepovets Metallurgical Combines.The fundamentals of the new process are that a lime coating in a converter is refractory and at the same time it is used for refining of the steel and there is a reduction in the addition of lump converter lime and the share of hot metal (as a result of the increase in the share of scrap) to the heat by a value approximately equal to the weight of the applied lime coating or of its soluble portion if the coating does not wear during a single heat.The basic stages of formation of refractory slag-forming coatings were described by us earlier in simplified form [6]. The kinetics of the processes which occur in sintering of powders in tne presence of a liquid phase depend significantly upon the size of the particles being sintered, the quantity of liquid phase, the degree of wetting of the solid phase by the liquid, the mutual solubility of the phases, the porosity of the particles, and the density of their packing [9]. With an insignificant quantity of binder (5-10% of the weight of lime) after fusion of it contact necks in which the basic processes determining the kinetics of sintering and the physiochemical parameters of the coating occur are formed between the lime particles.If it is assumed that a particle of lime and the liquid binder between it and the surface of the lining are two semiinfinite spaces and a rod located between them and brought at the moment of time T = 0 into contact and that the binder does not react with the binder,...
UDC 666.92:[669.!84~225o~66~ 2~At present torch guniting, which was developed in the 70~s in the US$~ ~l~ ~ ~s ~eimg improved in two directions. The first is intensification of the processes of combustion of the flame for the purpose of increasing the life of the periclase coatings [I], and the sec ~ ond is conversion to guniting with inexpensive and readily available materials (primarily lime) for partial or complete replacement of periclase powders in guniting mixtures [5,6].The first direction is accomplished in the following manner.By selecting the forms of fuel [I, 7] or by changing the design of the heads of multinozzle guniting guns [4,8] a reduction in coating porosity is obtained.However, with packing the periclase coating starts to spall and therefore additional measures for elimination of thermal failure of gunited coatings become necessary.These include additions to the guniting mixture of slags and oxides of iron [i] or aluminum [2] or guniting with thin layers [3]. The latter measure is not always possible under the conditions of organization of work in converter shops, and additions of oxides lead to a reduction in the slag resistance of the applied layers. Until now there have been no examples of a positive solution of this problem on a production scale~The second direction in improvement in torch guniting is accomplished by application to the working surface of converter linings of refractory slag-forming coatings.This process was developed by the All-Union Institute for Refractories and by the Azov Steel, Western Siberia, and Cherepovets Metallurgical Combines.The fundamentals of the new process are that a lime coating in a converter is refractory and at the same time it is used for refining of the steel and there is a reduction in the addition of lump converter lime and the share of hot metal (as a result of the increase in the share of scrap) to the heat by a value approximately equal to the weight of the applied lime coating or of its soluble portion if the coating does not wear during a single heat.The basic stages of formation of refractory slag-forming coatings were described by us earlier in simplified form [6]. The kinetics of the processes which occur in sintering of powders in tne presence of a liquid phase depend significantly upon the size of the particles being sintered, the quantity of liquid phase, the degree of wetting of the solid phase by the liquid, the mutual solubility of the phases, the porosity of the particles, and the density of their packing [9]. With an insignificant quantity of binder (5-10% of the weight of lime) after fusion of it contact necks in which the basic processes determining the kinetics of sintering and the physiochemical parameters of the coating occur are formed between the lime particles.If it is assumed that a particle of lime and the liquid binder between it and the surface of the lining are two semiinfinite spaces and a rod located between them and brought at the moment of time T = 0 into contact and that the binder does not react with the binder,...
In modern metallurgy questions related to repair of worn refractory linings of thermal equipment, prolongation of the service lives of refractories at the user, and application of protective and refractory coatings by different methods are of great interest.Such methods of application of coatings as plasma, detonation, and gas-flame spraying and torch guniting used in various branches of production are widely known [i-3]. These methods are used in application of protective coatings on materials operating in aggressive media at high temperatures. The coatings are applied in high temperature gas flows in a broad range of velocities.Plasma spraying has found wide use in industry in the application of powders on the surface of a base material, as a rule metal. This method makes it possible to apply refractory oxides, to control the temperature and velocity of the plasma stream, and to use a broad range of sprayed materials including metals, ceramics, and organic materials. Plasma coatings possess high density and good adhesion with the base. The comparatively low productivity of the process, the noise in operation, and the intense ultraviolet radiation are disadvantages of the plasma method of spraying.In addition, the method is distinguished by the high cost of the equipment and high operating costs.In detonation spraying as the result of the explosion the oxygen-acetylene mixture ejects the powder particles being sprayed through the gun barrel in the direction of the surface being treated. The high temperature (4000~ and velocity of the particles (820 m/see) [2] makes it possible to obtain denser coatings than in plasma spraying. At the same time the temperature of the base material remains low, which eliminates deformation of it or other physical changes. The strong noise in application makes it necessary to use remote control of the process with the equipment located in a special chamber. Among the disadvantages of the method are the high cost of equipment and the low productivity.The gas flame method, which has found the widest use, is distinguished by its simplicity and low cost of equipment. In the gas flame method the temperature of the flame reaches 3000~ which provides fusion of the basic refractory powders and thereby increases the density of the coating [2].All of the above methods have a common disadvantage, their low productivity.The most promising method of application of repair coatings in metallurgy is torch guniting, which has been developed in the USSR. The metallurgists of many countries of the World have shown interest in it. Using this method the guniting compound is delivered by the transporting gas from the feeder into the jet of a fuel-oxygen flame, heated to the plastic state in it, and deposited in the form of a coating on the lining of the metallurgical equipment. It should be noted that this method was developed for the hot repair and prolongation of the service life of steel melting equipment [4].
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