Using phenylphosphinic acid/zinc hydroxystannate nanoparticle-decorated graphene to enhance the flame retardancy and smoke suppressive performance of epoxy resin

Wang, Hongni; Su, Fangfang; Wang, Zehao; Xin, Yangyang; Yao, Dongdong; Zheng, Yaping

doi:10.1039/d2nj04694f

Cited by 5 publications

(3 citation statements)

References 44 publications

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“…The TSP and pSPR of SBR3 with ZHS@BN replacing part of ADP were 0.213 m 2 /s and 16.4 m 2 , respectively, which were 50.6% and 33.1% lower than those of SBR1, respectively. The main reason was that the BN sheet in the carbon layer had a barrier effect, and ZHS had a smoke suppression effect, 30 which effectively inhibited the generation of smoke.…”

Section: Resultsmentioning

confidence: 99%

The effects of zinc hydroxystannate/boron nitride hybrids and aluminum diethylphosphinate on flame retardancy and smoke suppression of styrene–butadiene rubber composites

Xu,

Zhang,

Cheng

et al. 2023

J of Applied Polymer Sci

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As one of the three general rubbers, styrene–butadiene rubber (SBR) is widely used in industrial products such as tires and cables. However, SBR has the disadvantages of flammability and low thermal conductivity, which limits its application in industry. In order to improve the flame retardancy and thermal conductivity of SBR, zinc hydroxystannate/boron nitride hybrids (ZHS@BN) were successfully prepared by in‐situ growth on BN. ZHS@BN was successfully prepared as determined by Fourier transform infrared spectroscopy, x‐ray diffraction, scanning electron microscopy and thermogravimetry. When 3 phr ZHS@BN and 12 phr aluminum diethylphosphinate (ADP) were added, the limiting oxygen index value of SBR composites reached 28.4%. Compared with pure SBR, their peak heat release rate and peak smoke release rate decreased by 59.2% and 50.6%, respectively. Through the analysis of the flame‐retardant properties and carbon residue of the SBR composites, it was proved that there was a good synergy between ZHS@BN and ADP to improve the flame‐retardant properties of SBR.

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Section: Resultsmentioning

confidence: 99%

The effects of zinc hydroxystannate/boron nitride hybrids and aluminum diethylphosphinate on flame retardancy and smoke suppression of styrene–butadiene rubber composites

Xu,

Zhang,

Cheng

et al. 2023

J of Applied Polymer Sci

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show abstract

“…Furthermore, it is proved that metal oxides are beneficial to enhance the smoke suppression of the polymer matrix. [30][31][32] This work aims to develop an HIFR by attaching TA, spherical CuO and polydimethylsiloxane (PDMS) to the surface of APP in turn. The resulting HIFR was incorporated into TPU to investigate the mechanical, thermal, and flame-retardant properties of composites.…”

Section: Introductionmentioning

confidence: 99%

“…Furthermore, it is proved that metal oxides are beneficial to enhance the smoke suppression of the polymer matrix. 30–32…”

Section: Introductionmentioning

confidence: 99%

Facile preparation of a hydrophobic intumescent flame retardant toward simultaneously enhanced flame retardancy and smoke suppression of thermoplastic polyurethane

Yuan,

Wang,

Fang

et al. 2023

New J. Chem.

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A strategy to synthesize phosphorus-containing nickel phyllosilicate whiskers to enhance the flame retardancy of epoxy composites with excellent mechanical and dry-friction properties

Nie,

Zhao,

et al. 2024

Front. Chem. Sci. Eng.

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Using phenylphosphinic acid/zinc hydroxystannate nanoparticle-decorated graphene to enhance the flame retardancy and smoke suppressive performance of epoxy resin

Abstract: The flammability of epoxy resin (EP) extremely hampers its practical applications. To circumvent it, a graphene-based flame retardant (MZP-GO) was successfully synthesized by incorporating phosphorus, zinc, tin, and molybdate elements...

Cited by 5 publications

References 44 publications

The effects of zinc hydroxystannate/boron nitride hybrids and aluminum diethylphosphinate on flame retardancy and smoke suppression of styrene–butadiene rubber composites

The effects of zinc hydroxystannate/boron nitride hybrids and aluminum diethylphosphinate on flame retardancy and smoke suppression of styrene–butadiene rubber composites

Facile preparation of a hydrophobic intumescent flame retardant toward simultaneously enhanced flame retardancy and smoke suppression of thermoplastic polyurethane

A strategy to synthesize phosphorus-containing nickel phyllosilicate whiskers to enhance the flame retardancy of epoxy composites with excellent mechanical and dry-friction properties

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