“…4 We have extensively investigated the composition, structure and stability of TM-Al single crystal systems ͑TM = Fe,Ti,Zr,Co,Ni,Pd,Ag͒ over the last several years. [5][6][7][8][9][10] For most of the systems studied, intermixing of TM atoms with the single-crystal Al substrate was observed in the first few monolayers of TM deposition before the onset of growth of TM rich films. In previous studies of interface intermixing of sputter-deposited polycrystalline bilayers, a large amount of intermixing was observed for many TM/Al systems at room temperature.…”