Use of X-ray photoelectron and Mössbauer spectroscopies in the study of iron pentacyanide complexes

Superconducting property and Fe valence state of FeSe thick films grown from high temperature solution

“…After the deduction of background with the Shirley function, two peaks can be deconvoluted at 707.8 eV and 706.6 eV, respectively. The former was close to the value of Fe in the polarized ionic bonds, such as in Na 3 Fe(CN) 5 NH 3 [13], while the later had the typical value in the metallic bondings, such as in pure Fe metal [14]. For comparison, the XPS graph of a sintered powder sample is also shown in Fig.…”

Facile synthesis and optical properties of Prussian Blue microcubes and hollow Fe2O3 microboxes

“…1b, the center of electron binding energy of C 1s is 284.18 eV, and the main peak of the N 1s (Fig. 1d) corelevel spectra is fitted with three components at 402.38, 399.28, and 397.28 eV, signifying the existence of C-N ([Fe (CN) 6 ] 4 À ) in the samples [20]. On the basis of the higherresolution spectra of C 1s, N 1s and Fe 2p, we could conclude that Prussian Blue nanocrystals were successfully synthesized.…”

Microbial synthesis of hollow porous Prussian blue@yeast microspheres and their synergistic enhancement of organic pollutant removal performance

“…For Fe 2p spectra of the sample (Fig. 3c) 38 In the case of N 1s spectra (Fig. 3d), the peaks of N 1s spectra were tted with three components at 397.6, 399.7 and 401.32 eV, suggesting the existence of C-N in PB NPs together with aminelike (-NH-) and positively charged nitrogen (N + ) structure in yeast.…”