Abstract. Methods of calorimetric analysis are used to study the dynamics of the hydration processes of concretes with different accelerator contents. The efficiency of the isothermal calorimetry method is shown for study of strength kinetics of concrete mixtures of accelerated hardening, promising for additive technologies in civil engineering.
IntroductionNowadays the use of additive technologies in construction industry is one of the most actual subjects of research. Growth of interest in such technologies in construction is conditioned by a number of factors: high level of production automation, improvement of production quality, acceleration of creation processes, possibility of optimization of CAD models, reduction of production wastes [1]. These factors represent a great interest for the application of additive technologies in civil engineering and use of 3D prototyping in place of the traditional methods of construction.The main problem for the use of additive technologies in construction is the materials used, since the ordinary concrete does not meet the requirements of 3D printing productivity [2]. Special composition for building printing should harden quickly enough to withstand the weight of subsequently deposited layers without deformation. Composites that harden for a long time slow down the process of erecting the building and cannot meet the requirements of 3D printing productivity [1]. There is a need to select and determine the optimal composition of accelerating additives to reduce the setting time of the concrete mixture.A large number of recent works on the control of setting time show the relevance of this subject of research. Shakor P [3] uses a printed composition based on a mixture of ordinary Portland cement (32.2%) and high aluminate cement (67.8%) with the addition of a lithium carbonate accelerator (4.5%). Lithium carbonate provides hardening acceleration, high early strength and good adhesion. Kazemian A et al [4] examine the effect of the accelerating additive based on calcium chloride on the workability of the concrete mixture for the building 3D printer. It is noted that increasing the dose of accelerator from 2% to 3% has no significant effect on the loss of workability of concrete in the first 90 minutes after the preparation of the mixture. In addition to the accelerators, retarders of setting time are also widely used to maintain the concrete mixture in the liquid state for the time necessary for the extrusion of the material. Retarders and accelerators of the setting time are added at different stages of production [5]. Sulphoaluminate cement could be used as an accelerator. In the work [6] a mixture of ordinary Portland cement (93%) with a sulphoaluminate cement additive (7%) is studied as a working