Use of Allylbenzene and Allyl Phenyl Ether as Chain-Transfer Agents in Radical Polymerization

Kudyshkin, V. O.; Вохидова, Н. Р.; Bozorov, N. I.; Sidorenko, O. E.; Ruban, I. N.; Воропаева, Н. Л.; Рашидова, С. Ш.

doi:10.1023/b:rjac.0000044130.01483.f7

Cited by 7 publications

(3 citation statements)

References 0 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Fluorescence investigations by Chee et al [38] confirms the expanded coil to compact globule transition for PNVCL; however, occurring over a wide temperature range of ca. 15 °C, while that of PNIPAAm occurs within a 2 °C range. Furthermore, the magnitude of conformational change is smaller for PNVCL.…”

Section: Poly(n-vinylcaprolactam) (Pnvcl)mentioning

confidence: 95%

Poly(N-vinylcaprolactam), a comprehensive review on a thermoresponsive polymer becoming popular

Cortez-Lemus

Licea‐Claveríe

2016

Progress in Polymer Science

315

327

View full text Add to dashboard Cite

Section: Poly(n-vinylcaprolactam) (Pnvcl)mentioning

confidence: 95%

Poly(N-vinylcaprolactam), a comprehensive review on a thermoresponsive polymer becoming popular

Cortez-Lemus

Licea‐Claveríe

2016

Progress in Polymer Science

315

327

View full text Add to dashboard Cite

“…2. Table 1 contains experimental data [27]. The numerical data on the reactivity are the following: (i) allyl benzene Q x =0.0072 e x =−0.83; and (ii) allyl phenyl ester Q x =0.0044, e x =−0.87.…”

Section: Descriptorsmentioning

confidence: 99%

Prediction of the Q-e parameters from structures of transfer chain agents

et al. 2015

View full text Add to dashboard Cite

The empirical parameters of copolymerization Q-e have been examined as an endpoint for establishing the quantitative structure -property relationships (QSPRs). The possibility to build up QSPR for these parameters is demonstrated for 22 transfer chain agents. Data for 20 taken in the literature and two were investigated in direct experiment. The statistical qualities of the models for parameter e together with the negative decimal logarithm of Q×10 −4 (pQ) are quite good. The mechanistic interpretation for these models are suggested and discussed.

show abstract

“…Olefins are versatile compounds used in coatings, plasticizers, organic synthesis, and polymerisation [1][2][3][4][5] . Although biomass is an important renewable carbon source for producing chemicals or fuels, reports on synthesising olefins via hydrodeoxygenation from biomass are limited [6][7][8][9][10] .…”

mentioning

confidence: 99%

Selective hydrodeoxygenation of α, β-unsaturated carbonyl compounds to alkenes

Wang,

Xin,

Chen

et al. 2024

Nat Commun

View full text Add to dashboard Cite

Achieving selective hydrodeoxygenation of α, β-unsaturated carbonyl groups to alkenes poses a substantial challenge due to the presence of multiple functional groups. In this study, we develop a ZnNC-X catalyst (X represents the calcination temperature) that incorporates both Lewis acidic-basic sites and Zn-Nx sites to address this challenge. Among the catalyst variants, ZnNC-900 catalyst exhibits impressive selectivity for alkenes in the hydrodeoxygenation of α, β-unsaturated carbonyl compounds, achieving up to 94.8% selectivity. Through comprehensive mechanism investigations and catalyst characterization, we identify the Lewis acidic-basic sites as responsible for the selective hydrogenation of C=O bonds, while the Zn-Nx sites facilitate the subsequent selective hydrodeoxygenation step. Furthermore, ZnNC-900 catalyst displays broad applicability across a diverse range of unsaturated carbonyl compounds. These findings not only offer valuable insights into the design of effective catalysts for controlling alkene selectivity but also extend the scope of sustainable transformations in synthetic chemistry.

show abstract

Use of Allylbenzene and Allyl Phenyl Ether as Chain-Transfer Agents in Radical Polymerization

Cited by 7 publications

References 0 publications

Poly(N-vinylcaprolactam), a comprehensive review on a thermoresponsive polymer becoming popular

Poly(N-vinylcaprolactam), a comprehensive review on a thermoresponsive polymer becoming popular

Prediction of the Q-e parameters from structures of transfer chain agents

Selective hydrodeoxygenation of α, β-unsaturated carbonyl compounds to alkenes

Contact Info

Product

Resources

About