Green
liquor dregs (GLD) are a major waste of the pulp and paper
industry, and their correct classification is important to finding
alternatives to landfill disposal. In the European Union, the methodology
to determine the hazard property HP 14 (“ecotoxic”)
is under discussion. Although biological tests are likely more representative
of wastes’ environmental behavior, there are still no official
guidelines on procedures, and ecotoxicity classification relies on
the chemical composition. This work aimed to evaluate the ecotoxicity
of GLD to determine HP 14. The assessment comprised a chemical analysis
(using ClassifyMyWaste software) and a battery of biotests targeting
aquatic ecosystems (Lepidium sativum, Aliivibrio
fischeri, Raphidocelis subcapitata, Lemna minor, and Daphnia magna). The chemical
analysis denoted GLD as a “Possible Hazard,” while the
battery of biotests showed high ecotoxic effects for three out of
five organisms, the most sensitive being Lepidium sativum, Lemna minor, and Daphnia magna. The pH correction of tested eluates to neutral values did not modulate
the noticed effects. Globally, the results suggest that GLD should
be classified as ecotoxic. Though, the European waste legislation
should provide guidelines to apply the end-of-waste criteria and avoid
landfilling even for materials like GLD.