In order to determine the ability of erbium to give a saturated green color, luminescent properties of Er3+ in the thiogallates
MGa2S4 false(M=normalCa,normalSr,normalBafalse)
MLaGa3S7 false(M=normalCa,normalSrfalse)
, and
La5/3Ga3S7
have been investigated. For efficient u.v. or cathodic excitation, the erbium charge transfer band must lie at longer wavelength than the lattice absorption edge; this is the case for the
MGa2S4
phases. Three processes can contribute to the population of the green emitting levels,
2H11/2
,
4S3/2
: direct transfer from the charge transfer band, multiphonon transitions, and cross‐relaxations. Multiphonon relaxation probabilities increase in the sequence
CaGa2S4