Ursache und Verlauf der spontanen Zersetzung von Trichloräthylen durch Aluminium

Metz, Ludwig; Roedig, Alfred

doi:10.1002/cite.330210908

Cited by 11 publications

(2 citation statements)

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“…Bei Gegenwart von Lewis-Sauren neigt Tri starker als Per zur Oligomerisierung (28)(29)(30). Selbst bei -10 OC fuhrt A1C13 zur Chlorwasserstoffentwicklung, bei 7 0 OC kann die Reaktion heftig verlaufen.…”

Section: Perchlore Thylenunclassified

Für das korrosive Verhalten wichtige chemische Eigenschaften des Perchlorethylens, Trichlorethylens und 1,1,1‐Trichlorethans – Eine Übersicht

Köser

Lübke

1980

Materials & Corrosion

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Section: Perchlore Thylenunclassified

Für das korrosive Verhalten wichtige chemische Eigenschaften des Perchlorethylens, Trichlorethylens und 1,1,1‐Trichlorethans – Eine Übersicht

Köser

Lübke

1980

Materials & Corrosion

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“…In small amounts the chlorocarbon I11 has been isolated among other products from the reaction of trichloroethylene with aluminum (168), from the condensation of trichloroethylene with chloroform and aluminum chloride (189,194), from the thermal dechlorination of octachloro-l,3-pentadiene (114,115), and from the thermal chlorination of 1 ,1,2,5,6,6-hexachloro-l,3,5-hexatriene (228). ( 168,190,194,196,197,199,220,221,224,229,230); 183-184°C. (17,159,189);…”

Section: \ /mentioning

confidence: 99%

The Chemistry Of Perchlorocyclopentenes And Cyclopentadienes

Ungnade¹,

McBee²

1958

Chem. Rev.

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Chloroethylenes

Snedecor¹,

Hickman²,

Mertens³

2004

Kirk-Othmer Encyclopedia of Chemical Technology

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The physical and chemical properties, manufacturing methods, uses, environmental concerns, and toxicity of 1,2‐dichloroethane are discussed. 1,2‐Dichloroethylene, also known as acetylene dichloride, dio‐form, α,β ‐dichloroethylene, and sym ‐dichloroethylene, exists in two isomers cis[156‐59‐2] and trans[156‐59‐2]. This solvent is used as an extraction solvent and as a chemical intermediate for other chlorinated solvents and compounds. The article describes the manufacturing, chemical and physical properties, storage and handling, toxicity, and its common uses. Trichloroethylene, commonly referred to as “tri”, is a widely used vapor‐degreasing solvent. In recent years its popularity has fallen mostly because of environmental restrictions on its use. Trichloroethylene has excellent solvency properties for a large number of natural and synthetic substances. This article includes physical and chemical properties, production, and use information. In addition, safety, toxicological, and environmental regulations pertinent to trichloroethylene are reviewed. Tetrachloroethylene [127‐18‐4], perchloroethylene, tetrachloroethene, commonly referred to as “perc,” is widely used in the dry‐cleaning industry as well as metal cleaning and vapor degreasing because of its excellent solvent properties. It has no flash point or flammable limits in air or oxygen. This article includes the physical and chemical properties of tetrachloroethylene, historical production within the United States, manufacturing locations and processes, as well as typical quality specifications. In addition, safety and toxicological considerations and environmental regulations pertinent to tetrachloroethylene are reviewed. The Montreal Protocol has had an impact on all of the compounds discussed in this article.

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Ursache und Verlauf der spontanen Zersetzung von Trichloräthylen durch Aluminium

Cited by 11 publications

References 0 publications

Für das korrosive Verhalten wichtige chemische Eigenschaften des Perchlorethylens, Trichlorethylens und 1,1,1‐Trichlorethans – Eine Übersicht

Für das korrosive Verhalten wichtige chemische Eigenschaften des Perchlorethylens, Trichlorethylens und 1,1,1‐Trichlorethans – Eine Übersicht

The Chemistry Of Perchlorocyclopentenes And Cyclopentadienes

Chloroethylenes

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