2020
DOI: 10.1039/d0ma00058b
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Urchin-like NiCoP coated with a carbon layer as a high-performance electrode for all-solid-state asymmetric supercapacitors

Abstract: The NiCoP@C-ULAs composite with high conductivity, abundant pores and good physical structure shows high specific capacity and excellent cycling stability.

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Cited by 14 publications
(8 citation statements)
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“…More importantly, the CoNiP and CoP 2 active sites in the synthesized CNP‒CP‐150 electrode enable numerous reversible redox reactions in the measured potential range in the alkaline electrolyte. The corresponding equations are provided below [ 2 , 20 ] …”
Section: Resultsmentioning
confidence: 99%
See 1 more Smart Citation
“…More importantly, the CoNiP and CoP 2 active sites in the synthesized CNP‒CP‐150 electrode enable numerous reversible redox reactions in the measured potential range in the alkaline electrolyte. The corresponding equations are provided below [ 2 , 20 ] …”
Section: Resultsmentioning
confidence: 99%
“…More importantly, the CoNiP and CoP 2 active sites in the synthesized CNP‒CP‐150 electrode enable numerous reversible redox reactions in the measured potential range in the alkaline electrolyte. The corresponding equations are provided below [ 2a,20 ] CoNiP+2normalOHCoPxOH+NiP1xOH+2e\begin{equation}{\rm{CoNiP }} + 2{\rm{O}}{{\rm{H}}^ - } \rightleftharpoons {\rm{Co}}{{\rm{P}}_x}{\rm{OH}} + {\rm{Ni}}{{\rm{P}}_{1 - x}}{\rm{OH}} + 2{{\rm{e}}^ - }\end{equation} CoPxOH+normalOHCoPxnormalO+H2normalO+e\begin{equation}{\rm{Co}}{{\rm{P}}_x}{\rm{OH}} + {\rm{O}}{{\rm{H}}^ - } \rightleftharpoons {\rm{Co}}{{\rm{P}}_x}{\rm{O}} + {{\rm{H}}_2}{\rm{O}} + {{\rm{e}}^ - }\end{equation}…”
Section: Resultsmentioning
confidence: 99%
“…as well as conductive high-molecular-weight polymers (polyaniline, polypyrrole, polythiophene, etc.) is considered to be an effective approach compared to elemental doping. In addition, a recent drive toward the development of 1D carbon nanofibers (CNFs) has attracted more attention for the fabrication of next-generation high-performance flexible SC devices because of their intrinsic advantages such as light weight, high surface area, and excellent mechanical/chemical stability. , Kalai Selvan et al have synthesized CNF-encapsulated NiCoP via an electrospin technique and extracted a specific capacitance of 333 Fg –1 in a three-electrode system. However, they used poly­(vinylidene difluoride) as a binder to fabricate the electrode, which hinders the active sites of the electrode material and thereby reduces the electrochemical performance.…”
Section: Introductionmentioning
confidence: 99%
“…5(c) and Table S2 in the ESI †). [66][67][68][69][70][71][72] Also, NF/CS4 yielded capacities of 936, 894, 816, 729, 612, and 579.4 C g −1 at 1, 2, 5, 10, 15, and 20 A g −1 , respectively, which are higher than that of NF/Co-MOF (Fig. 5 We compared the rate capability of NF/Co(CO 3 ) 0.5 (OH), NF/Co-MOF, NF/CS4, and NF/CS4-FCP30 from 1 to 20 A g −1 (Fig.…”
Section: Resultsmentioning
confidence: 99%