Uranyl ion coordination polymers with the dibenzobarrelene-based rac- and (R,R)-trans-9,10-dihydro-9,10-ethanoanthracene-11,12-dicarboxylate ligands

Abstract

Trans-9,10-dihydro-9,10-ethanoanthracene-11,12-dicarboxylic acid (deadcH2), in its racemic or R,R enantiomeric forms, has been used to synthesize eight uranyl ion complexes under solvo-hydrothermal conditions. [UO2(deadc)].1.5CH3CN (1) and [H2NMe2]2[(UO2)2(deadc)3].2H2O (2) crystallize as monoperiodic...