Abstract:The spent nuclear fuel has radioactive species such as actinides and lanthanides which hamper its reprocessing. This issue is undertaken by designing suitable organic ligands to strip off actinides from lanthanides. Due to the versatility of phenanthroline‐derived N, O‐donor ligands, we have looked into the electronic structure of N,O‐hybrid 1,10‐phenanthroline derived phosphine oxide ligands with various cyclic substitutions. The complexation behavior of these ligands with Am(III) and Eu(III) is evaluated usi… Show more
This feature article introduces phenanthroline-derived extractants for Ln(iii)/An(iii) separation and provides insights and guidance for future development.
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