Unveiling thecb‐typeIntramolecular [3+2] Cycloaddition Reactions of Fluorinated Azomethine Ylides to Ester Carbonyls with a Molecular Electron Density Theory Perspective
Abstract:The carbenoid‐type (cb‐type) intramolecular [3+2] cycloaddition (IM32CA) reactions of four fluorinated azomethine ylides (AYs) bearing an ester carbonyl substituent have been studied from the molecular electron density theory (MEDT) perspective. The presence of two fluorine atoms in these species changes the pseudodiradical structure of the simplest AY to that of a carbenoid one, according to the cb‐type molecular reactivity of these IM32CA reactions. These IM32CA reactions present low activation energies, les… Show more
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