“…417 Further investigations of radical trapping of vinylic radicals with nitric oxide should be carried out preferably using flow systems and low-temperature trapping of the reaction products. In similar fashion, β-substituted nitrosoalkenes are intermediates [419][420][421] that form during the trimethylsilylation reaction of nitroalkanes, where the initial product is a silyl nitronate (Scheme 32). A further example of a nitrosoalkene intermediate is found in the silylation of methyl 3-nitropropionate.…”
Section: Reaction Of Vinylic Radicals With Nitric Oxidementioning
confidence: 99%
“…In similar fashion, β-substituted nitrosoalkenes are intermediates − that form during the trimethylsilylation reaction of nitroalkanes, where the initial product is a silyl nitronate (Scheme ). A further example of a nitrosoalkene intermediate is found in the silylation of methyl 3-nitropropionate …”
Section: 103 13-nc-elimination Of Trialkylsilanols From Silyl
Nitronatesmentioning
“…417 Further investigations of radical trapping of vinylic radicals with nitric oxide should be carried out preferably using flow systems and low-temperature trapping of the reaction products. In similar fashion, β-substituted nitrosoalkenes are intermediates [419][420][421] that form during the trimethylsilylation reaction of nitroalkanes, where the initial product is a silyl nitronate (Scheme 32). A further example of a nitrosoalkene intermediate is found in the silylation of methyl 3-nitropropionate.…”
Section: Reaction Of Vinylic Radicals With Nitric Oxidementioning
confidence: 99%
“…In similar fashion, β-substituted nitrosoalkenes are intermediates − that form during the trimethylsilylation reaction of nitroalkanes, where the initial product is a silyl nitronate (Scheme ). A further example of a nitrosoalkene intermediate is found in the silylation of methyl 3-nitropropionate …”
Section: 103 13-nc-elimination Of Trialkylsilanols From Silyl
Nitronatesmentioning
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