Unusual transformations of methyl ?-nitropropionate upon reaction with silylating agents

Danilenko, V. M.; Ioffe, Sema L.; Strelenko, Yu. À.; Karpenko, N. F.; Калинин, А. В.; Тартаковский, В. А.

doi:10.1007/bf00957355

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Reaction Of Vinylic Radicals With Nitric Oxide1

103 13-nc-elimination Of Trialkylsilanols From Silyl Nitronates1

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“…417 Further investigations of radical trapping of vinylic radicals with nitric oxide should be carried out preferably using flow systems and low-temperature trapping of the reaction products. In similar fashion, β-substituted nitrosoalkenes are intermediates [419][420][421] that form during the trimethylsilylation reaction of nitroalkanes, where the initial product is a silyl nitronate (Scheme 32). A further example of a nitrosoalkene intermediate is found in the silylation of methyl 3-nitropropionate.…”

Section: Reaction Of Vinylic Radicals With Nitric Oxidementioning

confidence: 99%

“…In similar fashion, β-substituted nitrosoalkenes are intermediates − that form during the trimethylsilylation reaction of nitroalkanes, where the initial product is a silyl nitronate (Scheme ). A further example of a nitrosoalkene intermediate is found in the silylation of methyl 3-nitropropionate …”

Section: 103 13-nc-elimination Of Trialkylsilanols From Silyl Nitronatesmentioning

confidence: 99%

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