Abstract:The Debye relaxation is the main signal in the dielectric measurements of monoalcohols arising from the hydrogen-bonded superstructures, but its physics remains to be cleared. In this work, a monoalcohol of 4-methyl-2-pentanol is studied using dielectric spectroscopies recorded at high pressures. The dynamic parameters of the Debye and structural relaxations are extracted. The calculation of the Kirkwood factor of the Debye relaxation indicates chain-like H-bond molecular configurations. Remarkably, we found t… Show more
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