Untersuchungen über das Komplexchemische Verhalten des Berylliums. III

Fricke, R.; Rode, O.

doi:10.1002/zaac.19261520135

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1928

2016

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Cited by 6 publications

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“…These can be categorized into room‐temperature stable and unstable towards the loss of HCN, which indicates the strength of interaction. For example, the beryllium chloride adduct, [BeCl 2 (HCN) 4 ], easily loses HCN upon warming, whilst pnictogen fluoride HCN adducts, [EF 5 (HCN)] (E=As, Sb) are thermally quite stable solids, which degrade at temperatures of 85 °C or higher …”

Section: Methodsmentioning

confidence: 99%

See 1 more Smart Citation

A 1D Coordination Polymer of UF₅ with HCN as a Ligand

Scheibe

Rudel

Buchner

et al. 2016

Chemistry A European J

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β-Uranium(V) fluoride was reacted with liquid anhydrous hydrogen cyanide to obtain a 1D coordination polymer with the composition 1∞ [UF (HCN) ], 1∞ [UF F - (HCN) ], revealed by single-crystal X-ray structure determination. The reaction system was furthermore studied by means of vibrational and NMR spectroscopy, as well as by quantum chemical calculations. The compound presents the first described polymeric HCN Lewis adduct and the first HCN adduct of a uranium fluoride.

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Section: Methodsmentioning

confidence: 99%

“… Selection of known transition metal and main group halide Lewis adducts with HCN as a ligand: a) beryllium chloride HCN adduct; b) boron halide HCN adducts; c) hexaformonitriloiron(II) bis‐tetrachloridoferrate(III); d) titanium(IV) halide HCN adducts; e) niobium(V) halide cyanide acids; f) pnictogen(V) fluoride HCN adducts …”

Section: Methodsmentioning

confidence: 99%