Abstract:Die thermische Zersetzung von LiX · nH2O und LiX · nD2O (X = Cl, Br, J; n = 1, 2, 3) wird an einer Thermowaage untersucht. Es treten Unterschiede in den Abbaustufen auf in Abhängigkeit vom Ausgangshydrat und vom Anionenradius. Die thermische Stabilität sinkt mit steigendem Wassergehalt. Die Deuterate sind stabiler als die Hydrate.
“…A continuous equilibrium exists between KCl and H 2 O. In contrast, lithium salts are known to form LiX·nH 2 O (X = F, Cl, Br, I) hydrates [33,[70][71][72][73][74] (see Fig. 7).…”
Section: Mx·nh 2 O Hydrates (M = LI Na K and X = F Cl Br I)mentioning
confidence: 99%
“…8, example of DTA/TG curves obtained with LiCl·H 2 O). The decomposition temperatures of LiX·nH 2 O hydrates (X = Cl [33,70,71,72], Br [33,70,71], I [33,73,74]) have been measured by thermal analysis under inert gas (see Table 6). …”
Section: Mx·nh 2 O Hydrates (M = LI Na K and X = F Cl Br I)mentioning
“…A continuous equilibrium exists between KCl and H 2 O. In contrast, lithium salts are known to form LiX·nH 2 O (X = F, Cl, Br, I) hydrates [33,[70][71][72][73][74] (see Fig. 7).…”
Section: Mx·nh 2 O Hydrates (M = LI Na K and X = F Cl Br I)mentioning
confidence: 99%
“…8, example of DTA/TG curves obtained with LiCl·H 2 O). The decomposition temperatures of LiX·nH 2 O hydrates (X = Cl [33,70,71,72], Br [33,70,71], I [33,73,74]) have been measured by thermal analysis under inert gas (see Table 6). …”
Section: Mx·nh 2 O Hydrates (M = LI Na K and X = F Cl Br I)mentioning
Es werden die Schwingungsspektren und thermogravimetrischen Daten der Hydrate von LiBO2 angegeben und die Koordination der H2O‐Molekeln diskutiert.
Die Wassermolekeln der D2O‐Verbindungen werden bei etwas höheren Temperaturen abgespalten als diejenigen der H2O‐Verbindungen.
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