Abstract:This study explores the aerobic Baeyer-Villiger oxidation of
cyclohexanone into ε-caprolactone using metalloporphyrin and
benzaldehyde, a greener process to replace hazardous concentrated
peroxyacid. The reaction mechanism involves a series of free radical
reactions, identified through in-situ EPR. In this complex
three-component reaction, we developed an intrinsic kinetic model based
on the proposed mechanism. Utilizing a hyperbolic equation, the model
well fits experimental data, describing biomimetic cataly… Show more
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