Unravelling the Highest Magnetic Anisotropy Among all the nd-Shells in [WCp2]0 Metallocene
Sakshi Nain,
Aritra Mukhopadhyaya,
Md. Ehesan Ali
Abstract:Single-molecule magnets (SMMs) with a large magnetization reversal barrier are predominated by the lanthanide systems due to their strong spin−orbit coupling (SOC). However, the transition metals have also emerged as potential contenders and the largest magnetic anisotropy has been identified for a cobalt system among any d-series-based SMMs (Bunting et al. Science 2018, 362, eaat7319). In this work, we have explored the magnetic anisotropy in highly axial ligand field systems of metallocene, having different… Show more
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