The growing need for cleaner air
is gaining a lot of attention,
and therefore, the removal of organosulfur compounds from fuel with
a concentration less than 15 ppm is becoming the need of the hour.
To fulfill this expectation, we have synthesized an emergent class
of magnetic hybrid nanomaterials (Fe3O4/rGO
and Ni/Fe3O4/rGO) through a sol–gel-assisted
green synthetic technique that shows remarkable adsorptive desulfurization
of dibenzothiophene (DBT). The structural feature of the magnetic
nanomaterial was identified through various characterization techniques
like PXRD, FTIR, Raman, XPS, TGA, BET, SEM, and TEM. The magnetization
of Ni/Fe3O4/rGO confirmed that the adsorbents
performed well in magnetic separation. Further, doping with various
concentrations of Ni enhances its magnetization, thereby making the
recovery of nanocomposites easy, eco-friendly, and inexpensive with
the help of an external magnet. In contrast to an undoped nanocomposite,
Ni-doped Fe3O4/rGO exhibits superior properties.
Also, Ni-doped Fe3O4/rGO shows enhanced desulfurization
with an effective removal efficiency of 73% as compared with a pristine
nanocomposite (45%). This is because as the doping concentration of
Ni metal was increased, active Lewis acid sites were remarkably increased
which were favorably available for the transfer of lone pair electrons
on S atoms or π-electrons in the aromatic ring of thiophene
to form strong S–Ni bonding or π-complexation. With regard
to academic, industrial, and environmental considerations, Ni/Fe3O4/rGO is found to be a promising adsorbent and
can be the best replacement for adsorptive desulfurization due to
its relatively high adsorption capacity, improved magnetization, and
simple magnetic separation efficiency.