Herein,
carbon microspheres (CSs) of relatively uniform size from
waste biomass corn stalks without carbonization or activation were
first inserted as spacers to inhibit the restacking of graphene sheets
in carbon microsphere/reduced graphene oxide composite hydrogels (CS/rGOs).
The prepared composite hydrogels were applied as electrode materials
for supercapacitors and exhibited excellent electrochemical performance
due to their abundant oxygen-containing functional groups and good
hydrophilicity. Notably, the CS/rGO-3 sample-based symmetric supercapacitors
showed an excellent specific capacitance (281.5 F g–1 at 0.3 A g–1), a good rate performance (81.87%),
and an eminent capacitance retention rate (102.2% after 10,000 cycles
at 10 A g–1). Considering the commercial value of
corn stalks and their role in the field of carbon neutralization at
the same time, this work affords a new strategy for the high value-added
conversion of waste biomass and the preparation of high-performance
supercapacitor electrode materials.